Multilayer films
View Patent ↗Multilayer films comprising three or more layers have improved properties for a variety of applications. The multilayer films often have a total thickness of from about 10 to about 50 microns. Blown multilayer film properties may include excellent cling with reduced unwinding noise levels. Cast multilayer film properties include improved elasticity, impact, puncture, and tear properties.
1. A multilayer film comprising a thermoplastic polymer wherein said film has a total thickness of from about 10 to about 30 microns and wherein said film comprises from at least 10 to about 2000 layers, the film comprising:
10 or more layers each layer consisting of the same linear low density polyethylene with the same properties; and
each of the 10 or more layers is in direct contact with at least one other layer of the 10 or more layers wherein the multilayer film has a cross direction (CD) Elmendorf tear greater than 400 g.
2. The multilayer film of claim 1 wherein said film has a total thickness of from about 17 microns to about 30 microns.
3. The multilayer film of claim 1 wherein the linear low density polyethylene is an ethylene-octene copolymer.
4. The multilayer film of claim 1 further comprising an inner layer comprising a polypropylene-ethylene interpolymer.
5. The multilayer film of claim 4 wherein the density of the polypropylene-ethylene interpolymer is from about 0.85 g/cm 3 to 0.91 g/cm 3 according to ASTM D-792.
6. The multilayer film of claim 4 wherein the total crystallinity of the polypropylene-ethylene interpolymer is less than about 20%.
7. The multilayer film of claim 4 wherein the polypropylene-ethylene interpolymer is characterized by a melt flow rate of from about 5 g/10 min to about 10 g/10 min according to ASTM D1238 230° C./2.16 kg, a density of from about 0.84 g/cm 3 to about 0.87 g/cm 3 according to ASTM D-792, a DSC glass transition temperature of the polypropylene-ethylene interpolymer is less than about −20° C., and a total crystallinity of less than about 20%.
8. The multilayer film of claim 1 wherein the average cling of the film is greater than about 80 g according to ASTM D 5458.
9. The multilayer film of claim 1 wherein the Dart drop impact resistance is greater than about 150 g according to ISO 7765-1.
10. The multilayer film of claim 1 wherein the strain at break is greater than about 440% according to ISO 527-3/2000.
11. The multilayer film of claim 1 wherein the ultimate elongation is greater than about 440% according to ISO 527-3/2000.
12. The multilayer film of claim 1 wherein the puncture resistance at 250% is greater than about 0.4 kg according to ASTM D-5748.
13. The multilayer film of claim 1 comprising a release layer comprising of a linear low density polyethylene.
14. The multilayer film of claim 1 comprising a cling layer comprising a polyethylene.
15. The multilayer film of claim 1 comprising two outer layers, each outer layer comprising from 10% to 20% of the total film thickness.
16. The multilayer film of claim 1 wherein the film is a cast stretch film.
17. The multilayer film of claim 1 wherein the linear low density polyethylene is a heterogeneous linear low density polyethylene.
18. The multilayer film of claim 17 wherein the heterogeneous linear low density polyethylene is an ethylene-octene copolymer.