PSA tapes for splicing flat web materials
View Patent ↗The invention relates to pressure-sensitive adhesive tapes for flying splice of flat web materials, having at least one splittable carrier and two layers of adhesive, at least one of the adhesives being a silicone PSA, more particularly an electron-beam-crosslinked silicone PSA, and also to a method of producing them. The silicone PSA advantageously has at least one polydiorganosiloxane having the structure —Si(R 2 )—O—[Si(R 2 )—O] n —Si(R 2 )—, where the 2n+4 substituents R independently of one another are monovalent hydrocarbon radicals and n is an integer, and also at least one resin (“MQ resin”) constructed from (R 2 ) 3 SiO 1/2 — units (“M units”) and SiO 4/2 units (“Q units”), the substituents R 2 of the M units being independently of one another alkyl groups, alkenyl groups, alkylsilyl groups, hydroxyl groups or hydrogen.
1. Pressure-sensitive adhesive tape for flying splice of flat web materials, comprising at least one splittable carrier and two layers of adhesive, wherein at least one of the adhesives is an electron-beam crosslinked pressure-sensitive silicone adhesive.
2. Pressure-sensitive adhesive tape according to claim 1 , wherein the pressure-sensitive adhesive possesses an elastic component of at least 50% as determinable in the microshear travel test (test C).
3. Pressure-sensitive adhesive tape according to claim 1 , wherein said at least one pressure-sensitive silicone adhesive comprises
a) at least one polydiorganosiloxane having the structure
where
the 2n+4 substituents R independently of one another are monovalent hydrocarbon radicals and
n is an integer,
and also comprises
b) at least one resin (“MQ resin”) constructed from (R 2 ) 3 SiO 1/2 units (“M units”) and SiO 4/2 units (“Q units”)
where
the substituents R 2 of the M units independently of one another are alkyl groups, alkenyl groups, alkylsilyl groups, hydroxyl groups or hydrogen.
4. Pressure-sensitive adhesive tape for flying splice of flat web materials, comprising at least one splittable carrier and two layers of adhesive, wherein at least one of the adhesives is a pressure-sensitive silicone adhesive (silicone PSA) comprising
a) at least one polydiorganosiloxane of the formula
where
the two radicals R 1 are alkenyl groups chosen independently of one another,
the 2n+4 substituents R independently of one another are monovalent hydrocarbon radicals and
n is an integer,
b) at least one resin (“MQ resin”) constructed from (R 2 ) 3 SiO 1/2 units (“M units”) and SiO 4/2 units (“Q units”)
where
the substituents R 2 of the M units independently of one another are alkyl groups, alkenyl groups, alkylsilyl groups, hydroxyl groups or hydrogen,
c) at least one organohydrogenpolysiloxane which contains on average at least two silicon-bonded hydrogen atoms per polymer molecule and is free from olefinic double bonds, said at least one adhesive being electron-beam crosslinked.
5. Pressure-sensitive adhesive tape according to claim 4 , wherein the two radicals R 1 are vinyl groups and/or hexenyl groups chosen independently of one another.
6. Pressure-sensitive adhesive tape according to claim 4 , wherein the double bond of the alkenyl group is terminal, i.e. is located between the furthest-removed and the second-furthest-removed C atom of the alkenyl group, as seen from the Si atom on which the alkenyl group is located.
7. Pressure-sensitive adhesive tape according to claim 4 , wherein an average value for n is chosen such that the weight-average molecular weight M W of the polydiorganosiloxane (I) is in the range of 7×10 5 g/mol≦M W ≦8×10 5 g/mol.
8. Adhesive tape according to claim 4 , wherein a polydispersity D of the polydiorganosiloxane (I) is in the range of 2.0≦D≦2.2.
9. Pressure-sensitive adhesive tape for flying splice of flat web materials, comprising at least one splittable carrier and two layers of adhesive, wherein at least one of the adhesives is a pressure-sensitive silicone adhesive (silicone PSA) comprising
a) at least one polydiorganosiloxane of the formula
where
the two radicals R′ are chosen independently of one another from the group consisting of hydrogen and also unbranched and branched alkyl radicals having 1 to 6 carbon atoms and/or alkylsilyl radicals and/or alkyloxysilyl radicals,
the 2n+4 substituents R independently of one another are monovalent hydrocarbon radicals and
n is an integer,
b) at least one resin (“MQ resin”) constructed from (R 2 ) 3 SiO 1/2 units (“M units”) and SiO 4/2 units (“Q units”),
where
the substituents R 2 of the M units independently of one another are alkyl groups, alkenyl groups, alkylsilyl groups, hydroxyl groups or hydrogen, said at least one adhesive being electron-beam crosslinked.
10. Pressure-sensitive adhesive tape according to claim 9 , wherein the two substituents R′ are hydrogen atoms.
11. Pressure-sensitive adhesive tape according to claim 9 , wherein an average value for n is chosen such that the weight-average molecular weight M W of the polydiorganosiloxane (II) is in the range of 6.4×10 5 g/mol≦M W ≦1.0×10 6 g/mol.
12. Adhesive tape according to claim 9 , wherein a polydispersity D of the polydiorganosiloxane (II) is in the range of 2.3≦D≦2.8.
13. Pressure-sensitive adhesive tape according to claim 3 , wherein the substituents R are independently of one another selected from the group consisting of hydrocarbon radicals having 1 to 18 carbon atoms.
14. Pressure-sensitive adhesive tape according to claim 1 , wherein the substituents R are independently of one another selected from the group consisting of methyl groups, unsubstituted phenyl groups and substituted phenyl groups.
15. Pressure-sensitive adhesive tape according to claim 1 , wherein the MQ resin is one having a weight-average molecular weight M W of 500 g/mol≦M W ≦100,000 g/mol.
16. Method of producing the pressure-sensitive adhesive tape of claim 1 , comprising coating the at least one pressure-sensitive silicone adhesive onto at least one side of a carrier material and crosslinking on said carrier material with electron beams.
17. Method according to claim 16 , wherein said crosslinking is performed with an electron-beam dose of at least 10 kGy.
18. Method according to claim 17 , wherein said crosslinking is carried out up to a degree of crosslinking which corresponds to an elastic component of at least 50% as determinable in the microshear travel test (test C).