Organic electroluminescent device
View Patent ↗An organic electroluminescent device, which has, between a pair of electrodes, at least one organic layer including a light-emitting layer, in which the organic layer contains a specific tetraphenylene compound, and in which the light-emitting layer contains a phosphorescent material; and a specific tetraphenylene compound that can be used in the device.
1. An organic electroluminescent device, comprising, between a pair of electrodes, at least one organic layer comprising a light-emitting layer comprising a phosphorescent material,
wherein the organic electroluminescent device contains at least one compound represented by formula (1A):
wherein, in formula (1A), R 21 , R 22 , R 23 , R 24 , R 25 , R 26 , R 27 , R 28 , R 29 , R 30 , R 31 , R 32 , R 33 , R 34 , R 35 , and R 36 each represent a hydrogen atom or a substituent; and at least one of R 21 , R 22 , R 23 , R 24 , R 25 , R 26 , R 27 , R 28 , R 29 , R 30 , R 31 , R 32 , R 33 , R 34 , R 35 , and R 36 is a group having a Hammett σ p value of 0.05 or more.
2. The organic electroluminescent device of claim 1 , wherein the compound represented by formula (1A) is contained in the light-emitting layer.
3. The organic electroluminescent device of claim 1 , wherein the light-emitting layer comprises an electron-injecting/transporting compound.
4. The organic electroluminescent device of claim 3 , wherein the electron-injecting/transporting compound is a metal complex.
5. The organic electroluminescent device of claim 3 , wherein the electron-injecting/transporting compound is a heterocyclic compound comprising at least two nitrogen atoms.
6. The organic electroluminescent device of claim 1 , wherein the phosphorescent material is a transition metal complex.
7. The organic electroluminescent device of claim 1 , wherein the phosphorescent material is an orthometalated iridium complex.
8. The organic electroluminescent device of claim 1 , wherein at least one substituent selected from the group consisting of R 21 , R 22 , R 23 , R 24 , R 25 , R 26 , R 27 , R 28 , R 29 , R 30 , R 31 , R 32 , R 33 , R 34 , R 35 , and R 36 in formula (1A) represents a group containing a pyridine ring, benzimidazole ring, imidazopyridine ring, a fluorine atom or chlorine atom.
9. The organic electroluminescent device of claim 1 , wherein at least one substituent selected from the group consisting of R 21 , R 22 , R 23 , R 24 , R 25 , R 26 , R 27 , R 28 , R 29 , R 30 , R 31 , R 32 , R 33 , R 34 , R 35 , and R 36 in formula (1A) represents a group containing a pyridine ring, imidazopyridine ring or a fluorine atom.