Antioxidant compositions
View Patent ↗The invention relates to antioxidant compositions for lubricants and organic polymers comprising a first antioxidant comprising a reaction product of p-cresol, dicyclopentadiene and isobutylene; and a second antioxidant comprising a diarylamine. The first antioxidant preferably has the structure: wherein n is 0-50, and R 1 and R 2 are independently hydrogen, a straight or branched C 1 -C 30 alkyl or alkylene group optionally substituted with one or more substituents, C 3 -C 12 cycloalkyl, C 5 -C 12 aryl, or C 6 -C 12 alkylaryl. The second antioxidant preferably has the formula: (R 3 ) a —Ar 1 —NH—Ar 2 —(R 4 ) b wherein Ar 1 and Ar 2 are independently aromatic hydrocarbon groups and R 3 and R 4 are independently hydrogen or hydrocarbyl groups having from 6 to about 100 carbon atoms and a and b are independently 0 to 3 but (a+b) is not greater than 4.
1. A lubricant composition, comprising:
(a) a Group II and/or Group III base stock of lubricating viscosity; and
(b) from 0.5 to 1.5% by weight based on the weight of the lubricant composition of an antioxidant composition consisting of a first antioxidant which is a reaction product of p-cresol with dicyclopentadiene and isobutylene and having a molecular weight [g/mol] of 600-700, and a second antioxidant having the formula:
(R 3 ) a —Ar 1 —NH—Ar 2 —(R 4 ) b
wherein Ar 1 and Ar 2 are independently aromatic hydrocarbon groups and R 3 and R 4 are independently hydrogen or hydrocarbyl groups having from 6 to about 100 carbon atoms and a and b are independently 0 to 3 but (a+b) is not greater than 4 wherein the weight ratio of the second antioxidant to the first antioxidant is from 1:1 to 19:1, wherein at least 80% by weight of the lubricant composition is base stock a).
2. The lubricant composition of claim 1 , wherein the weight ratio of the second antioxidant to the first antioxidant is from 3:1 to 19:1.
3. The lubricant composition of claim 1 , wherein the lubricant composition comprises ZDDP in an amount no greater than 1 wt.%, based on the total weight of the lubricant composition.
4. The lubricant composition of claim 1 , wherein the lubricant composition comprises less than 0.7 wt.% ZDDP, based on the total weight of the lubricant composition.
5. The lubricant composition of claim 1 , further comprising at least one lubricating oil additive selected from the group consisting of antioxidants, anti-wear agents, detergents, rust inhibitors, dehazing agents, demulsifying agents, metal deactivating agents, friction modifiers, pour point depressants, antifoaming agents, co- solvents, package compatibilisers, corrosion-inhibitors, ashless dispersants, dyes, extreme pressure agents and mixtures thereof.
6. The lubricant composition of claim 1 , wherein the second antioxidant comprises a mixture of mono-, di- and tri-nonyl diphenylamine.
7. The lubricant composition of claim 1 , wherein the antioxidant composition is a liquid at 25° C.
8. The lubricant composition of claim 1 , wherein the antioxidant composition has a kinematic viscosity at 100° C. of less than 40 cSt.
9. The lubricant composition of claim 1 , wherein the composition comprises hindered phenolics of formula (III) in an amount less than 0.5 weight percent, based on the total weight of the antioxidant composition:
wherein R5, R6, and R7, the same or different, represent a linear or branched C1-C18 alkyl group.