Components joining method and components joining structure
View Patent ↗To provide a components joining method and a components joining structure which can realize joining of components while securing conduction at a low electrical resistance with high reliability. In a construction in which by using a solder paste containing solder particles 5 in a thermosetting resin 3 a , a rigid substrate 1 and a flexible substrate 7 are bonded by the thermosetting resin 3 a , and a first terminal 2 and a second terminal 8 are electrically connected by the solder particles 5 , a blending ratio of an activator of the thermosetting resin 3 a in the solder paste is properly set and oxide film removed portions 2 b , 8 b , and 5 b are partially formed in oxide films 2 a , 8 a , and 5 a of the first terminal 2 , the second terminal 8 , and the solder particles 5 . Thereby, the first terminal 2 and the second terminal 8 are electrically conducted by solder bonding the solder particles 5 to both the first terminal 2 and the second terminal 8 via the oxide film removed portions 2 b and 8 b , and while fusion of the solder particles 5 with each other is prevented in the thermosetting resin 3 a , connection of components at a low electrical resistance is realized with high reliability.
1. A components joining method for electrically connecting a first terminal and a second terminal to each other, wherein the first terminal and the second terminal are provided on a first part and a second part, respectively, and the surfaces of at least one of the first terminal and the second terminal are covered by a natural oxide film, and bonding the first part and the second part to each other, comprising the steps of:
interposing a solder paste containing solder particles consisting mainly of tin in a thermosetting resin between the first part and the second part, wherein the solder particles are covered with oxide films, and
electrically connecting the first terminal and the second terminal by the solder particles by pressing the first terminal and the second terminal against each other while heating the first part and/or the second part to form a solder portion between the first terminal and the second terminal and bonding the first part and the second part to each other by curing the thermosetting resin,
wherein the solder paste contains an acid anhydride as a curing agent for curing the thermosetting resin, and further contains an activator which removes the natural oxide films of the terminal surfaces and oxide films of the solder particles, in an amount of not more than 1 weight percent for a portion of the solder paste excluding the solder particles,
wherein the amount of the activator is set so that in the electrically connecting step the natural oxide film of the terminal surfaces and the oxide films of the solder particles are partially but not completely removed and the solder particles that do not contribute the formation of the solder portions remain covered by oxide films that are not removed by the activator, and in the bonding step the thermosetting resin is cured while the surface of the terminal are partially covered by the natural oxide film and the solder particles are partially covered by the oxide films.
2. The components joining method according to claim 1 , wherein the first terminal and the second terminal are made of copper (Cu) or a copper-based alloy.
3. The components joining method according to claim 1 , wherein the thermosetting resin thermally cures at a temperature higher than a melting point temperature of the solder.
4. The components joining method according to claim 1 , wherein the heating is performed at a temperature higher than the curing temperature of the thermosetting resin.
5. A solder paste to be used in a components joining method for electrically connecting a first terminal and second terminal to each other, wherein the first terminal and the second terminal are provided on a first part and a second part, respectively to form solder portions between the first terminal and the second terminal, wherein the surfaces of at least one of the first terminal and the second terminal are covered by natural oxide films,
wherein the solder paste contains a thermosetting resin containing solder particles consisting mainly of tin, an acid anhydride as a curing agent for the thermosetting resin, and an activator which removes the natural oxide films of the terminals and oxide films on the solder particles, wherein the activator is in an amount of not more than 1 weight percent for a portion of the solder paste excluding the solder particles,
wherein the amount of the activator is set so that the activator is capable of partially but not completely removing the natural oxide film of the terminal surfaces and the oxide films of the solder particles, and the solder particles that do not contribute the formation of the solder portions remain covered by oxide films that are not removed by the activator and the thermosetting resin is curable while the terminal surfaces are partially covered by the natural oxide film and the solder particles are partially covered by the oxide films.