Process for the modification of biodegradable polymers
View Patent ↗Process for the modification of a polymer or copolymer having the following general structure for one or more of the repeating units: (1) wherein n is an integer, m is an integer in the range 0 to 6, and R is selected from hydrogen, substituted or unsubstituted C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 aralkyl, and C 7 -C 20 alkaryl, which groups may include linear or branched alkyl moieties; the optional one or more substituents being selected from the group consisting of hydroxy, alkoxy, linear or branched alk(en)yl, aryloxy, halogen, carboxylic acid, ester, carboxy, nitrile, and amido groups, which process involves contacting the polymer or copolymer with a cyclic organic peroxide under conditions whereby at least some of said peroxide is decomposed. This process results in a (co)polymer with a high degree of branching but free of gel formation.
1. A process for the modification of a polymer or copolymer having the following general structure for one or more of the repeating units:
wherein n is an integer, m is an integer in the range 0 to 6, and R is selected from the group consisting of hydrogen, substituted or unsubstituted C l -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 aralkyl, and C 7 -C 20 alkaryl, which groups may include linear or branched alkyl moieties; the optional one or more substituents being selected from the group consisting of hydroxy, alkoxy, linear or branched alk(en)yl, aryloxy, halogen, carboxylic acid, ester, carboxy, nitrile, and amido groups,
the process comprising contacting the polymer or copolymer with a cyclic organic peroxide under conditions whereby at least some of said peroxide is decomposed and wherein the melt strength of the polymer or copolymer is improved.
2. The process according to claim 1 wherein the polymer or copolymer and the cyclic peroxide are contacted at a temperature in the range of 180-260° C.
3. The process according to claim 2 wherein the polymer or copolymer and the cyclic peroxide are contacted at a temperature in the range of 200-240° C.
4. The process according to claim 1 wherein the contacting comprises injecting the cyclic peroxide into a melt of the polymer or copolymer.
5. The process according to claim 1 wherein the cyclic peroxide is selected from the group consisting of cyclic ketone peroxides and 1,2,4-trioxepanes.
6. The process according to claim 1 wherein the polymer is polylactic acid.
7. The process according to claim 1 wherein the (co)polymer is present in a blend with one or more other (co)polymers or materials.
8. A modified polymer or copolymer having the following general structure for one or more of the repeating units:
wherein n is an integer, m is an integer in the range 0 to 6, and R is selected from the group consisting of hydrogen, substituted or unsubstituted C l -C 20 alkyl, C 3 - C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 aralkyl, and C 7 -C 20 alkaryl, which groups may include linear or branched alkyl moieties; the optional one or more substituents being selected from the group consisting of hydroxy, alkoxy, linear or branched alk(en)yl, aryloxy, halogen, carboxylic acid, ester, carboxy, nitrile, and amido groups, wherein the modified polymer or copolymer is obtained by the process of claim 1 .
9. A film, coating, or article comprising the modified polymer of claim 8 .
10. A composition comprising (i) a polymer or copolymer having the following general structure for one or more of the repeating units:
wherein n is an integer, m is an integer in the range 0 to 6, and R is selected from the group consisting of substituted or unsubstituted C l -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 aralkyl, and C 7 -C 20 alkaryl, which groups may include linear or branched alkyl moieties; the optional one or more substituents being selected from the group consisting of hydroxy, alkoxy, linear or branched alk(en)yl, aryloxy, halogen, carboxylic acid, ester, carboxy, nitrile, and amido groups; and (ii) a cyclic organic peroxide.
11. The process according to claim 3 wherein the contacting comprises injecting the cyclic peroxide into a melt of the polymer or copolymer.
12. The process according to claim 2 wherein the cyclic peroxide is selected from the group consisting of cyclic ketone peroxides and 1,2,4-trioxepanes.
13. The process according to claim 4 wherein the cyclic peroxide is selected from the group consisting of cyclic ketone peroxides and 1,2,4-trioxepanes.
14. The process according to claim 11 wherein the cyclic peroxide is selected from the group consisting of cyclic ketone peroxides and 1,2,4-trioxepanes.
15. The process according to claim 2 wherein the polymer is polylactic acid.
16. The process according to claim 4 wherein the polymer is polylactic acid.
17. The process according to claim 5 wherein the polymer is polylactic acid.
18. The process according to claim 2 wherein the (co)polymer is present in a blend with one or more other (co)polymers or materials.
19. The process according to claim 4 wherein the (co)polymer is present in a blend with one or more other (co)polymers or materials.
20. The process according to claim 5 wherein the (co)polymer is present in a blend with one or more other (co)polymers or materials.
21. The composition according to claim 10 wherein the cyclic peroxide is selected from the group consisting of cyclic ketone peroxides and 1,2,4-trioxepanes.