Preparation of acetic acid
View Patent ↗A process for producing acetic acid is disclosed. The process comprises carbonylating methanol to form a reaction mixture comprising a catalyst, catalyst stabilizer, acetic acid, methanol, methyl iodide, methyl acetate, water, and carbon monoxide and introducing at least a portion of the reaction mixture to a distillation column to separate into a bottom steam comprising the catalyst and catalyst stabilizer, a sidedraw stream comprising acetic acid and water, and an overhead stream comprising methanol, methyl acetate, methyl iodide, and water. The process of the invention eliminates the use of flash tank.
1. A process for producing acetic acid, said process comprising:
(a) carbonylating methanol in the presence of a catalyst selected from the group consisting of rhodium catalysts and iridium catalysts, catalyst stabilizer, water and methyl iodide to form a reaction mixture comprising the catalyst, catalyst stabilizer, acetic acid, methanol, methyl iodide, methyl acetate, and water; and
(b) withdrawing the reaction mixture and feeding it to a distillation column to separate into a bottom stream comprising the catalyst and catalyst stabilizer, a sidedraw stream comprising acetic acid and water, and an overhead stream comprising methanol, methyl acetate, methyl iodide, and water; wherein no flash tank is used between steps (a) and (b).
2. The process of claim 1 , wherein the bottom stream of step (b) is recycled to the carbonylation of step (a).
3. The process of claim 1 , wherein the overhead stream of step (b) is recycled to the carbonylation of step (a).
4. The process of claim 1 , wherein the overhead stream is phase-separated to a light, aqueous phase comprising water, acetic acid, and methyl acetate and a heavy, organic phase comprising methyl iodide and methyl acetate.
5. The process of claim 4 , wherein the heavy, organic phase is recycled to the carbonylation of step (a).
6. The process of claim 4 , wherein the light, aqueous phase is recycled to the distillation of step (b) or to the carbonylation of step (a).
7. The process of claim 1 , further comprising distilling the sidedraw stream to remove water.
8. The process of claim 1 , wherein the catalyst is a rhodium catalyst.
9. The process of claim 8 , wherein the catalyst stabilizer is selected from the group consisting of pentavalent Group VA oxides, metal iodide salts, and mixtures thereof.
10. The process of claim 8 , wherein the catalyst stabilizer is a phosphine oxide.
11. The process of claim 8 , wherein the catalyst stabilizer is triphenylphosphine oxide.
12. The process of claim 8 , wherein the catalyst stabilizer is a metal iodide salt.
13. The process of claim 8 , wherein the catalyst stabilizer is lithium iodide.
14. The process of claim 1 , wherein the concentration of water in step (a) is up to 10 wt % of the reaction mixture.