Method and system for hydrogen evolution and storage

1. A method for producing hydrogen (H 2 ), comprising exposing a chemical compound to a catalyst under conditions suitable for chemical reaction that forms hydrogen, the chemical compound having the formula

wherein Q is selected from the group consisting of —(C(R 7 R 8 )) n — where n is from 1 to 10, —(C(R 7 R 8 )-M-C(R 7 R 8 ))—, —(C(R 7 )═C(R 8 ))—, —(C(R 7 )═C(R 8 )—C(R 9 )═C(R 10 ))—, —(C(R 7 )═N)—, and —(C(R 7 )═N—C(R 8 )═N)—;

wherein M is selected from the group consisting of oxygen, —NR 9 —, sulfur, and —C(═O)—;

wherein Z is selected from the group consisting of oxygen, sulfur, and —N(R 11 )—;

wherein R 5 and R 11 are independently selected from the group consisting of hydrogen, alkyl, and aryl;

wherein R 7 , R 8 , R 9 , and R 10 are independently selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkyl carboxylic acid, alkyl sulfonic acid, alkyl phosphoric acid, alkyl phosphonic acid, aryl carboxylic acid, aryl sulfonic acid, aryl phosphoric acid, aryl phosphonic acid, alkenyl carboxylic acid, alkenyl phosphoric acid, and alkenyl phosphonic acid;

wherein R 6 is selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkyl carboxylic acid, alkyl sulfonic acid, alkyl phosphoric acid, alkyl phosphonic acid, aryl carboxylic acid, aryl sulfonic acid, aryl phosphoric acid, aryl phosphonic acid, alkenyl carboxylic acid, alkenyl phosphoric acid, alkenyl phosphonic acid, —OR 12 , —N(H)(R 12 ) and —N(R 12 R 13 ) wherein R 12 and R 13 are independently selected from the group consisting of hydrogen, alkyl and aryl;

wherein R 7 and R 8 may be connected to each other to form a ring structure;

wherein R 8 and R 9 may be connected to each other to form a ring structure; and

with the proviso that at least one of R 5 or R 11 is hydrogen.

2. The method of claim 1 , wherein the catalyst comprises palladium.

3. The method of claim 1 , wherein the catalyst comprises palladium particles, palladium supported on carbon, palladium supported on alumina, palladium supported on silica, a slurry of palladium in a solvent, a fluidized bed comprising palladium, a packed bed comprising palladium, or palladium carboxylate.

4. The method of claim 1 , wherein the catalyst comprises palladium carboxylate dissolved in acetonitrile, tetrahydrofuran, water, or mixtures thereof, or the product resulting from the reaction of palladium carboxylate with acetonitrile, tetrahydrofuran, water, or mixtures thereof.

5. The method of claim 1 , wherein Q is —(C(R 7 R 8 )-M-C(R 7 R 8 ))—, wherein R 7 is hydrogen, wherein R 8 is hydrogen, wherein M is —NR 9 —, wherein R 9 is hydrogen, wherein Z is —N(R 11 )—, and wherein R 11 is hydrogen.