Diluents for crosslinker-containing adhesive compositions
View Patent ↗The disclosure relates to an adhesive composition for bonding lignocellulosic substrates. The adhesive composition contains a crosslinker and a non-urea diluent where the non-urea diluent is present in an amount from about 0.01 to about 75 weight % based on the total wet weight of the composition and where the crosslinker contains essentially no formaldehyde. Also disclosed is the adhesive further containing. an aqueous mixture of a protein source. The disclosure also relates to a process for making lignocellulosic composites utilizing the disclosed adhesive composition and to the lignocellulosic composites made using the disclosed process.
1. An adhesive composition consisting essentially of a crosslinker, a non-urea diluent, and an aqueous mixture of a protein source, wherein the non-urea diluent is present in an amount from about 0.01 to about 75 weight % based on the total wet weight of the composition and wherein the crosslinker contains essentially no formaldehyde.
2. The adhesive composition as claimed in claim 1 , wherein the aqueous mixture of a protein source is obtained from a mixture of water and at least one product selected from the group consisting of soy flour, soy protein concentrate, soy protein isolate and mixtures thereof.
3. The adhesive composition as claimed in claim 1 , wherein the crosslinker is selected from the group consisting of a polyamidoamine-epichlorohydrin resin, a polyamine-ephichlorohydrin resin, an isocyanate, an epoxy, an aldehyde starch, an aldehyde, an aldehyde resin and mixtures thereof.
4. The adhesive composition of claim 1 , wherein the non-urea diluent is at least one selected from the group consisting of diethylene glycol, propylene glycol, 2-methoxyethanol, glycerol, a glycerol derivative, ethylene carbonate, propylene carbonate, methyl pyrollidone, low molecular weight polyethylene glycol and derivatives like methoxy polyethylene glycol, sucrose, lactose, sorbitol, maltodextrin, cyclodextrin, a carbohydrate, syrups and hydrolyzed polysaccharide, an inorganic salt, sodium sulfate, sodium phosphate, sodium chloride, alum, bentonite, an aluminosilicate, an alkali metal aluminosilicate, a water soluble organic compound, formamide, acetamide, N-methylpyrrolidinone, a surfactant, an emulsifier, an oil, vegetable oil, silicon oil and mineral oil.
5. The adhesive composition of claim 1 , wherein the non-urea diluent is selected form the group consisting of glycerol, sucrose, corn syrup, sorbitol, hydrogenated corn syrup and mixtures thereof.
6. The adhesive composition of claim 1 , wherein the protein in the protein source is present in an amount of from about 0.01% to about 50 weight % based on the total wet weight of the adhesive composition.
7. The adhesive composition of claim 1 , wherein the crosslinker is present in an amount of from about 0.01% to about 50 weight % based on the total wet weight of the adhesive composition.
8. The adhesive composition of claim 1 , wherein the non-urea diluent is present in an amount of from about 5 to about 60% by weight based on the total wet weight of the adhesive composition.
9. The adhesive composition of claim 1 , wherein the crosslinker is a polyamidoamine-epichlorohydrin.
10. The adhesive composition of claim 1 , wherein the adhesive composition has solids content in the range from about 5 to about 75 weight %.
11. The adhesive composition of claim 1 , wherein the weight ratio of protein to crosslinker is in the range of about 100:1 to about 0.1:1.
12. A method for producing a lignocellulosic composite comprising applying the adhesive composition of claim 1 , to a lignocellulosic substrate and curing the adhesive composition to form the lignocellulosic composite.
13. The method of claim 12 , wherein the adhesive composition is applied to the lignocellulosic substrate at a concentration of from about 1 to about 25 weight % based on the total weight of the adhesive composition and the lignocellulosic substrate.
14. The method of claim 12 , wherein pressure is applied during curing and wherein the pressure ranges from about atmospheric pressure to about 1000 psi.
15. The method of claim 12 , wherein the adhesive composition is cured at a temperature from about 50 to about 250° C.
16. The method of claim 12 , wherein the lignocellulosic substrate is at least one selected from the group consisting of groundwood pulp, sawdust, wood particles, wood strand, wood veneer, wood board, wood wafer and wood sheathing.
17. A lignocellulosic composite obtained from the process of claim 12 .
18. The lignocellulosic composite of claim 17 , wherein the lignocellulosic composite is selected from the group consisting of hardwood plywood, particleboard, medium density fiberboard, oriented strandboard, waferboard, fiberboard, parallel strand lumber, laminated strand lumber and a hardwood veneered product.