Method for recovering oil from an oil reservoir
View Patent ↗There is a method for enhancing the recovery of oil from a reservoir. The method has the step of a) introducing a flooding fluid into the reservoir and b) extracting the oil through a wellbore at a location different than the point of introduction of the flooding fluid into the reservoir. The flooding fluid has water and an amount of one or more non-polymeric viscoelastic surfactants sufficient to provide an interfacial surface tension of about 1 mNm or less and a viscosity of about 10 cps or more. The one or more surfactants is selected from the group of one or more cationic surfactants, one or more zwitterionic surfactants, one or more amphoteric surfactants, one or more anionic surfactants, and combinations thereof.
1. A method for flooding an oil-bearing reservoir, comprising:
a) introducing a flooding fluid into the reservoir, wherein the fluid has
i) water and
ii) an amount of one or more non-polymeric, viscoelastic surfactants sufficient to provide the flooding fluid with an oil/water interfacial surface tension of about 1 mN/m or less and a viscosity of about 10 cPs or more, wherein the one or more non-polymeric, viscoelastic surfactants is one or more cationic surfactants;
b) pushing oil through the reservoir to the vicinity of a wellbore at a location different than the point of introduction of the flooding fluid into the reservoir; and
c) extracting the oil through the wellbore.
2. The method of claim 1 , wherein the flooding fluid has about 0.1 wt % to about 20 wt % of the one or more non-polymeric surfactants.
3. The method of claim 1 , wherein the flooding fluid has about 0.5 wt % to about 10 wt % of the one or more non-polymeric surfactants.
4. The method of claim 1 , wherein the flooding fluid has up to about 20 lbs/1000 gals water of organic and inorganic salts.
5. The method of claim 1 , wherein the flooding fluid has an amount of the one or more surfactants sufficient to provide a flooding fluid having an interfacial surface tension of about 0.1 mN/m or less.
6. The method of claim 1 , wherein the one or more cationic surfactants has the formula
wherein R 1 is a hydrophobic moiety of alkyl, alkylarylalkyl, alkoxyalkyl, alkylaminoalkyl or alkylamidoalkyl, and wherein R 1 has from about 16 to about 22 carbon atoms and may be branched or straight-chained and saturated or unsaturated; wherein R 2 and R 3 are, independently, i) an aliphatic group or ii) an aliphatic group with an aromatic or benzylic moiety bonded therewith; wherein R 2 , R 3 , and R 5 have from 1 to about 30 atoms; wherein the aliphatic group is branched or straight-chained and saturated or unsaturated; and wherein X is a suitable counter-anion, such as Cl − , Br − , and CH 3 CH 3 SO 4 − .
7. The method of claim 6 , wherein the flooding fluid has about 0.5 wt % to about 10 wt % of the one or more non-polymeric surfactants.
8. The method of claim 7 , wherein the flooding fluid has an amount of the one or more surfactants sufficient to provide a flooding fluid having an interfacial surface tension of about 0.1 mN/m or less.
9. The method of claim 7 , wherein the flooding fluid has an amount of the one or more surfactants sufficient to provide a flooding fluid having an interfacial surface tension of about 0.1 mN/m or less.
10. The method of claim 1 , wherein the one or more cationic surfactants has the formula
wherein R 1 is a hydrophobic moiety of alkyl, alkylarylalkyl, alkoxyalkyl, alkylaminoalkyl or alkylamidoalkyl, and wherein R 1 has from about 16 to about 22 carbon atoms and may be branched or straight-chained and saturated or unsaturated; wherein R 2 and R 3 are, independently, i) an aliphatic group or ii) an aliphatic group with an aromatic or benzylic moiety bonded therewith.
11. The method of claim 10 , wherein the flooding fluid has about 0.5 wt % to about 10 wt % of the one or more non-polymeric surfactants.