Phosphor and manufacturing method for the same, and light source
View Patent ↗To provide a phosphor having an emission spectrum with a broad peak in a range from yellow color to red color (580 nm to 680 nm) and an excellent excitation band on the longer wavelength side from near ultraviolet/ultraviolet of excitation light to visible light (250 nm to 550 nm), and having an improved emission intensity. The phosphor is provided, which is given by a general composition formula expressed by MmAaBbOoNn:Z, (wherein element M is more than one kind of element having bivalent valency, element A is more than one kind of element having tervalent valency selected from the group consisting of Al, Ga, In, Tl, Y, Sc, P, As, Sb, and Bi, element B is more than one kind of element having tetravalent valency, O is oxygen, N is nitrogen, and element Z is more than one kind of element selected from rare earth elements or transitional metal elements, satisfying m>0, a>0, b>0 o≧0, and n=2/3m+a+4/3b−2/3o), and further containing boron and/or fluorine.
1. A phosphor, which is given by a general composition formula expressed by MmAaDbOoNn:Z, (wherein element M is at least one kind of element having bivalent valency, element A is at least one kind of element having tervalent valency selected from the group consisting of Al, Ga, In, Tl, Y, Sc, P, As, Sb, and Bi, element D is at least one kind of element having tetravalent valency, O is oxygen, N is nitrogen, and element Z is at least one kind of element selected from rare earth elements or transitional metal elements, expressed by m=a=b=1 and n=2/3m+a+4/3b−2/3o), and further containing fluorine or boron and fluorine.
2. A manufacturing method of a phosphor, containing a phosphor crystal which is given by a general composition formula expressed by MmAaDbOoNn:Z, (wherein element M is at least one kind of element having bivalent valency, element A is at least one kind of element having tervalent valency selected from the group consisting of Al, Ga, In, Tl, Y, Sc, P, As, Sb, and Bi, element D is at least one kind of element having tetravalent valency, O is oxygen, N is nitrogen, and element Z is at least one kind of element selected from rare earth elements or transitional metal elements, and further containing fluorine or boron and fluorine expressed by m=a=b=1, and n=2/3m+a+4/3b−2/3o),
said method comprising the steps of:
weighing and mixing the raw materials in an inert atmosphere to manufacture a mixture;
firing this mixture to manufacture a fired substance, and
pulverizing this fired substance to manufacture the phosphor,
wherein a fluorine compound or a boron compound and a fluorine compound are further added to a raw material for forming the phosphor expressed by the composition formula MmAaDbOoNn:Z.
3. A light source, comprising the phosphor according to claim 1 , and a light emitting part.
4. The light source according to claim 3 , wherein a wavelength range of light emitted from the light emitting part is 250 nm to 550 nm.
5. The light source according to claim 3 , wherein an LED (light emitting diode) is used as the light emitting part.
6. A manufacturing method of the phosphor having the structure of claim 1 , comprising the steps of:
weighting and mixing a compound containing the element M, the compound containing the element A, the compound containing the element Z or a simple substance of the element Z, and a fluorine compound or a boron compound and a fluorine compound, to obtain a mixture;
firing the mixture to manufacture a fired object; and
pulverizing the fired object, to obtain the phosphor,
wherein a fluorine compound containing 100 ppm or less content of Fe or a boron compound and a fluorine compound containing 100 ppm or less content of Fe are used.
7. The manufacturing method of the phosphor according to claim 6 , wherein
a nitride of group II expressed by a general formula M 3 N 2 containing 100 ppm or less of element Fe is used as the compound containing the element M.
8. The manufacturing method of the phosphor according to claim 7 , wherein
the nitride of group II is manufactured by nitriding a simple substance of 2N or more containing 100 ppm or less Fe is used, in a nitrogen atmosphere or in an ammonia atmosphere at the temperature of 300° C. or more.