Method of producing nanophosphor particles
View Patent ↗Provided is a method of producing spherical nanophosphor particles having a uniform size distribution. When nanophosphor obtained using the method is used in a flat panel display, the flat panel display has higher screen brightness and a higher resolution.
1. A method of producing nanophosphor, consisting essentially of:
dissolving a phosphor starting material in a solvent, wherein the solvent optionally includes a surface-active agent, and adding a precipitating agent thereto, thereby producing a phosphor precursor;
wherein the phosphor starting material consists essentially of a compound represented by ML3 where M is at least one selected from the group consisting of Y, La, Eu, Gd, Tb, Er, Yb and any mixtures thereof and L comprises Cl, Br NO3, OCH3, OC2H5, OC3H7, or OC4H9 or any mixtures thereof; and at least one selected from the group consisting of H3BO3, boron hydride, an organic boron compound, H3PO4, NH4H2PO4, (NH4)2HPO4, NaVO3, NH4VO3 and any mixtures thereof;
treating the phosphor precursor with an inorganic salt;
heat-treating the phosphor precursor treated with the inorganic salt to produce nanophosphor particles; and
removing the inorganic salt by washing.
2. The method of claim 1 , wherein the solvent comprises at least one selected from the group consisting of water, aliphatic monool, aliphatic diol, aliphatic triol, and any mixtures thereof.
3. The method of claim 1 , wherein the step of adding the precipitating agent is performed while heating.
4. The method of claim 1 , wherein the heating is performed with a microwave oven.
5. The method of claim 1 , wherein the precipitating agent is a basic compound.
6. The method of claim 1 , wherein the solvent includes a surface-active agent and the surface-active agent comprises at least one material selected from the group consisting of citric acid, acetic acid, sodium acetate, ammonium acetate, oleic acid, sodium oleate, ammonium oleate, ammonium succinate, polyacrylate, glycine, acyl glutamate, and mixtures thereof.
7. The method of claim 1 , wherein, in the treating the phosphor precursor with the inorganic salt, a space between neighboring phosphor precursor particles is filled with the inorganic salt.
8. The method of claim 1 , wherein the inorganic salt is in a saturated aqueous solution.
9. The method of claim 1 , wherein the inorganic salt comprises at least one material selected from the group consisting of NaBO2, LiBO2, KBO2, MgSO4, Li2SO4, Na2SO4, K2SO4, MgCl2, CaCl2, SrCl2, BaCl2, LizCO3, NazCO3, K2CO3, RbzCO3, LiCl, NaCl, KC1, RbC1, CsCl, and any mixtures thereof.
10. A method of producing a YBO3-based nanophosphor consisting essentially of:
dissolving a phosphor starting material consisting essentially of an yttrium(Y) source compound and a boron(B) source compound in a solvent, wherein the solvent optionally includes a surface-active agent, and adding a precipitating agent thereto, thereby producing a phosphor precursor;
wherein the yttrium(Y) source compound is represented by YL3; and L is at least one selected from the group consisting of Cl, Br, NO3, OCH3, OC2H5, OC3H7, OC4H9 and any mixtures thereof;
treating the phosphor precursor with an inorganic salt;
heat-treating the phosphor precursor treated with the inorganic salt to produce YBO3- based nanophosphor particles; and
removing the inorganic salt by washing.
11. The method of claim 10 , wherein the boron(B) source compound comprises at least one material selected from the group consisting of H3BO3, boron hydride, an organic boron compound and any mixtures thereof.
12. The method of claim 10 , wherein the step of adding the precipitating agent is performed while heating.
13. The method of claim 12 , wherein the heating is performed using a heating technique within a microwave oven.
14. The method of claim 10 , wherein, in the treating the phosphor precursor with the inorganic salt, a space between neighboring phosphor precursor particles is filled with the inorganic salt.
15. The method of claim 10 , wherein the inorganic salt is in the form of a saturated aqueous solution.
16. The method of claim 10 , wherein the inorganic salt comprises at least one material selected from the group consisting of NaBO2, LiBO2, KBO2, MgSO4, Li2SO4, Na2SO4, K2SO4, MgCl2, CaCl2, SrCl2, BaCl2, Li2CO3, Na2CO3, K2CO3, Rb2CO3, LiCl, NaCl, KCl, RbCl, CsCl and any mixtures thereof.