Water treatment method
View Patent ↗A water treatment method according to the present invention comprises adding an amphoteric polymer flocculant to polluted water to flocculate suspended solids so that the polluted water becomes treated water, and filtering the treated water. An inorganic flocculent can be added to the treated water after flocculation treatment before filtering the treated water.
1. A water treatment method comprising:
first, adding at least one inorganic flocculant to polluted water before at least one amphoteric polymer flocculant is added to the polluted water,
subsequently, adding the at least one amphoteric polymer flocculant to polluted water to flocculate suspended solids so that the polluted water becomes treated water,
at last, adding at least one inorganic flocculant to the treated water, and
filtering the treated water,
wherein the filtration is provided by at least one membrane selected from the group consisting of a microfiltration membrane, an ultrafiltration membrane, and sand, and
wherein a mole ratio of anionic units and cationic units in the amphoteric polymer flocculant is from 15/1 to 1/5.
2. The water treatment method according to claim 1 , wherein the polluted water is river water, aggregate washed waste water, oil field excavated waste water, paper and pulp waste water, biological treatment water of organic waste water, or a combination thereof.
3. The water treatment method according to claim 1 , wherein the amphoteric polymer flocculant comprises at least one anionic group and at least one cationic group in a molecule.
4. The water treatment method according to claim 1 , wherein the amphoteric polymer flocculant is obtained by polymerizing at least one anionic monomer and at least one cationic monomer.
5. The water treatment method according to claim 1 , wherein the amphoteric polymer flocculant is obtained by polymerizing at least one anionic monomer, at least one cationic monomer and at least one nonionic monomer.
6. The water treatment method according to claim 4 , wherein the cationic monomer is a neutralized salt or a quaternary salt of dialkylaminoethyl (meth)acrylates.
7. The water treatment method according to claim 4 , wherein the anionic monomers is a vinyl monomer comprising a carboxy group.
8. The water treatment method according to claim 7 , wherein the vinyl monomer is at least one selected from the group consisting of acrylic acid, methacrylic acid, and maleic acid.
9. The water treatment method according to claim 1 , wherein the amphoteric polymer flocculant has a intrinsic viscosity of 5 dl/g or more, and the intrinsic viscosity is measured at 30° C. in 1N sodium nitrate aqueous solution.
10. The water treatment method according to claim 5 , wherein a mass ratio of nonionic monomers to the total mass of anionic monomers and cationic monomers is from 15/1 to 1/9.
11. The water treatment method according to claim 1 , wherein a content of the amphoteric polymer flocculant is 0.05 mg/l or more based on the amount of the polluted water.
12. The water treatment method according to claim 1 , wherein the inorganic flocculant is at least one selected from the group consisting of polyaluminum chloride (PAC), aluminum sulfate, ferric chloride, and polyiron sulfate.
13. The water treatment method according to claim 1 , wherein a content of the inorganic flocculant is from 1 to 50 mg/l based on the amount of the treated water.