Bicyclic enamino(thio)carbonyl compounds
View Patent ↗The present invention relates to novel bicyclic enamino(thio)carbonyl compounds, to processes for their preparation and to their use for controlling animal pests, especially arthropods, in particular insects.
1. A bicyclic enaminocarbonyl compound of formula (I)
in which
A represents a radical selected from the group consisting of 6-chloropyrid-3-yl; 6-bromopyrid-3-yl; 6-methylpyrid -3-yl; 6-trifluoromethylpyrid-3-yl; 2-methylpyrimidin-5-yl; 2-chloropyrimid-5-yl; 1H-pyrazol-4-yl, which is optionally substituted in the 1-position by methyl or ethyl and in the 3-position by chlorine; 1H-pyrazol-5-yl; 3-methylpyrazol-5-yl; 2-bromo-1,3-thiazol-5-yl; 2-chloro-1,3-thiazol-5-yl; isoxazol-5-yl, which is optionally substituted in the 3-position by methyl, ethyl, chlorine or bromine; 3-methyl-1,2,4-oxadiazol-5-yl; 1-methyl-1,2,4-triazol-3-yl; 1,2,5-thiadiazol -3-yl; 5-fluoro-6-chloropyrid-3-yl; 5,6-dichloropyrid-3-yl; 5-bromo-6-chloropyrid-3-yl; 5-fluoro-6-bromopyrid-3-yl; 5-chloro-6-bromopyrid-3-yl; 5,6-dibromopyrid-3-yl; 5-methyl-6-chloropyrid-3-yl; 5-methyl-6-iodopyrid-3-yl; and 5-difluoromethyl-6-chloropyrid-3-yl,
B represents oxygen or methylene,
E represents CH or C-alkyl,
D 1 -Z-D 2 as a group represent —CH 2 —CH 2 —, —HC═CH—, —CH 2 —CH 2 —CH 2 —, —CH 2 —C(═CH 2 )—CH 2 —, —CH 2 —CO—CH 2 —, —CH 2 —CH(OH)—CH 2 —, —CH 2 —CF 2 —CH 2 —, —CH 2 —CHF—CH 2 —, —CH 2 —CHCl—CH 2 —, —CH═CH—CH 2 —, —CH 2 —CH 2 —CH═, —CH 2 —CH 2 —CH(OH)—, —CH 2 —CH(CH 3 )—CH 2 —, —CH 2 —CH 2 —CH 2 —CH 2 —, —CH 2 —CH═CH—CH 2 —, —CH 2 —O—CH 2 —, —CH 2 —CH 2 —O—, —CH 2 —N(CH 3 )—CH 2 —, —CH 2 —CH 2 —N(CH 3 )—, or —CH 2 —S—CH 2 —,
R 1 represents hydrogen,
R 2 represents hydrogen, fluorine, or chlorine, and
Q represents oxygen.
2. A composition, comprising at least one compound of formula (I) according to claim 1 and a customary extender and/or surfactant.
3. A method for controlling pests, comprising allowing a compound of formula (I) according to claim 1 to act on the pests and/or a habitat thereof.
4. A composition for controlling pests comprising a compound according to claim 1 .
5. A method for controlling pests comprising allowing a composition according to claim 2 to act on the pests and/or a habitat thereof.
6. The bicyclic enaminocarbonyl compound of the formula (I) according to claim 1 wherein
A represents a radical selected from the group consisting of 6-chloropyrid-3-yl, 6-bromopyrid -3-yl, 2-chloropyrimid-5-yl, 5-fluoro-6-chloropyrid-3-yl, 5,6-dichloropyrid-3-yl, 5-fluoro -6-bromopyrid-3-yl, and 2-chloro-1,3-thiazol-5-yl,
B represents oxygen, and
D 1 -Z-D 2 as a group represents —CH 2 —CH 2 —CH 2 —, —CH 2 —C(═CH 2 )—CH 2 —, —CH 2 —C(CH 3 )—CH 2 —, —CH 2 —CH 2 —CH 2 —CH 2 —, —CH 2 —CH═CH—CH 2 —, —CH 2 —O—CH 2 —, —CH 2 —CH 2 —O—, —CH 2 —CHF—CH 2 —, —CH 2 —CHCl—CH 2 —, —CH═CH—CH 2 —, —CH 2 —CH 2 —CH═, or —CH 2 —CH 2 —CH(OH)—.
7. A composition comprising at least one bicyclic enaminocarbonyl compound of the formula (I) according to claim 6 and a customary extender and/or surfactant.
8. A method for controlling pests, comprising allowing a compound of the formula (I) according to claim 6 to act on the pests and/or habitat thereof.
9. A method for controlling pests comprising allowing a composition according to claim 7 to act on the pests and/or their habitat thereof.
10. A composition for controlling pests comprising a compound according to claim 6 .
11. The bicyclic enaminocarbonyl compound of the formula (I) according to claim 1 wherein
A represents 6-chloropyrid-3-yl or 2-chloro-1,3-thiazol-5-yl,
B represents oxygen or methylene,
E represents CH or C-alkyl,
D 1 -Z-D 2 represents —CH 2 —CH 2 —CH 2 —, —CH 2 —C(═CH 2 )—CH 2 —, —CH 2 —CO—CH 2 —, —CH 2 —CH(OH)—CH 2 —, —CH 2 —CHF—CH 2 —, —CH 2 —CHCl—CH 2 —, —CH═CH—CH 2 —, —CH 2 —CH 2 —CH═, —CH 2 —CH 2 —CH(OH)—, —CH 2 —CH(CH 3 )—CH 2 —, —CH 2 —CH 2 —CH 2 —CH 2 —, —CH 2 —CH═CH—CH 2 —, —CH 2 —O—CH 2 —, or —CH 2 —CH 2 —O—,
R 1 represents hydrogen,
R 2 represents hydrogen, fluorine, or chlorine, and
Q represents oxygen.
12. A composition comprising at least one bicyclic enaminocarbonyl compound of the formula (I) according to claim 11 and a customary extender and/or surfactant.
13. A method for controlling pests, comprising allowing a compound of the formula (I) according to claim 11 to act on the pests and/or habitat thereof.
14. A method for controlling pests comprising allowing a composition according to claim 12 to act on the pests and/or their habitat thereof.
15. A composition for controlling pests comprising a compound according to claim 11 .