IP Library Granted Patent US 7,935,751
Granted Patent B2
US 7,935,751 · App. 12/295,531 · Granted May 3, 2011

Weatherable polyolefin nanocomposites

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Quick Facts
Patent No.
US 7,935,751
App. No.
12/295,531
Granted
May 3, 2011
Kind
B2
Abstract

A method is disclosed concerning discovering how the use of an additive in a polyolefin compound affects the weatherability of that compound. Applying that technique, a weatherable polyolefin nanocomposite is disclosed, which contains UV stabilizers that filter wavelengths in a range influenced by presence of organoclay in the nanocomposite.

Claims (21)

1. A method of discovering how the use of an additive in a polyolefin compound affects the weatherability of that compound, comprising the steps of:

(a) exposing the compound containing the additive with an absorption filter at a specific wavelength for a specific amount of time;

(b) exposing the same compound containing the additive without the absorption filter at the specific wavelength for the specific amount of time;

(c) repeating steps (a) and (b) with different filters at different wavelengths to determine what wavelengths cause degradation or crazing of the compound;

(d) selecting a material that absorbs at the wavelengths in a range influenced by presence of the additive in the compound which cause degradation or crazing of the compound containing both the polyolefin and the additive.

2. The method of claim 1 , wherein the compound is a weatherable polyolefin nanocomposite and wherein the nanocomposite comprises:

(a) polyolefin

(b) organoclay,

(c) compatibilizer, and

(d) UV stabilizers that filter wavelengths in a range influenced by presence of organoclay in the polyolefin nanocomposite.

3. The method of claim 2 , wherein polyolefin comprises any of homopolymers, copolymers, blends of polymers, mixtures of polymers, alloys of polymers, and combinations thereof, where at least one of the polymers is polymerized from an olefin monomer having 2 to 8 carbon atoms.

4. The method of claim 3 , wherein the polyolefin comprises wherein the polyethylene comprises low-density polyethylene, high-density, high molecular weight polyethylene, ultra-high molecular weight polyethylene, linear-low-density polyethylene, very-low density polyethylene, maleated polypropylene, polypropylene, polybutylene, polyhexene, polyoctene, and copolymers thereof, and ethylene-vinyl-acetate copolymer, and mixtures, blends or alloys of any of them.

5. The method of claim 2 , wherein the nanocomposite, further comprised an impact modifier.

6. The method of claim 5 , wherein the impact modifier is selected from the group consisting of natural rubber, polyisoprene rubber, styrene-butadiene rubber, polybutadiene rubber, nitrile rubber, butyl rubber, ethylene-propylene-diene rubber (EPDM), ethylene-propylene copolymer, ethylene-hexene copolymer, ethylene-octene copolymer, and combinations thereof.

7. The method of claim 2 , wherein the organoclay is montmorillonite clay intercalated with an organic or semi-organic chemical.

8. The method of claim 2 , wherein the compatibilizer is maleic anhydride grafted polypropylene.

9. The method of claim 2 , wherein the UV stabilizer is a chemical which has good absorption above 320 nm.

10. The method of claim 9 , wherein the UV stabilizer chemical filters light above 320 nm.

11. The method of claim 10 , wherein the UV stabilizer is a benzotriazole or a monomeric high molecular weight, sterically hindered amine light stabilizer.

12. The method of claim 2 , wherein the composite further includes optional additives.

13. The method of claim 2 , wherein the composite further includes optional polymers.

Assignments (6)
RELEASE OF SECURITY INTERESTS IN PATENTS RECORDED AT REEL 027522, FRAME 0154. Recorded Jun 24, 2025
From: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
To: AVIENT CORPORATION (F/K/A POLYONE CORPORATION); GSDI SPECIALTY DISPERSIONS, INC. (F/K/A GAYSON SILICON DISPERSIONS, INC.); THE COLORMATRIX CORPORATION; COLORMATRIX HOLDINGS, INC.
Reel/Frame 071711/0354 →
RELEASE (REEL 027456 / FRAME 0779) Recorded Nov 18, 2015
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: POLYONE CORPORATION
Reel/Frame 037129/0199 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL 027450 FRAME 0907 Recorded Feb 28, 2013
From: BANK OF AMERICA, N.A., AS AGENT
To: POLYONE CORPORATION
Reel/Frame 029900/0240 →
SECURITY AGREEMENT Recorded Dec 29, 2011
From: POLYONE CORPORATION
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 027456/0779 →
SECURITY AGREEMENT Recorded Dec 28, 2011
From: POLYONE CORPORATION
To: BANK OF AMERICA, N.A.
Reel/Frame 027450/0907 →
SECURITY AGREEMENT Recorded Dec 23, 2011
From: POLYONE CORPORATION; GAYSON SILICONE DISPERSIONS, INC.; COLORMATRIX CORPORATION, THE; COLORMATRIX HOLDINGS, INC.
To: WELLS FARGO CAPITAL FINANCE, LLC
Reel/Frame 027522/0154 →