Process for the preparation of an artificial latex
View Patent ↗A process of producing an artificial latex, comprising the steps: (a) cement formation, wherein a rubber is dissolved in a suitable hydrocarbon solvent; (b) emulsification of the cement formed in step (a), together with an aqueous soap solution, thus forming an oil-in-water emulsion; (c) hydrocarbon solvent removal, resulting in a latex of the rubber having particles of a median particle size in the range of from about 0.5 to 2.0 μm, and optionally (d) latex concentration, forming an artificial latex with a higher solids content, characterized in that in step (b) a premix is formed first, which is subsequently homogenized into an oil-in-water emulsion, and wherein the premix is formed by mixing the cement with the aqueous soap solution at a volume ratio of 1:1.5 to 1:3 using at least one homogenizer comprising a stator and a rotor, that is operated at a tip speed of the outer ring of the rotor in the range of from 8 to 16 m/s, and wherein the premix is subsequently homogenized in a rotor/stator homogenizer operated at a tip speed of the outer ring of the rotor in the range of from 16 to 35 m/s.
1. A process of producing an artificial latex, comprising the steps:
(a) dissolving polyisoprene rubber in n-pentane solvent wherein the amount of polyisoprene rubber dissolved in the n-pentane solvent is less than about 20 percent by weight thereby forming a cement;
(b) emulsifying the cement with an aqueous rosin soap solution, wherein the rosin soap concentration is from 0.5 to 5.0% by weight in water and the volume ratio of aqueous soap solution versus cement is from 1:2.0 to 1:2.5 thus forming an oil-in-water emulsion; and
(c) removing the n-pentane solvent, resulting in a latex of the polyisoprene rubber having particles of as median particle size in the range of from about 0.5 to 2.0 μm, wherein in step (b) a premix is formed first, wherein a first rotor/stator homogenizer is used for the preparation of the premix, wherein said first homogenizer is operated at a tip speed of the outer edge of the rotor/stator homogenizer in the range of 8 to 16 meters/second, and wherein the premix is subsequently homogenized in a second rotor/stator homogenizer operated at a tip speed of the outer edge of the rotor in a range from 18 to 30 meters/second into said oil-in-water emulsion using said second separate rotor/stator homogenizer for the subsequent preparation of the oil-in-water emulsion, wherein the premix is made in a continuous manner and the premix is recycled more than 5 times but less than 25 times and further including a product outlet after said second homogenizer, wherein the first and second rotor/stator homogenizers are part of a recycle loop further containing a holding vessel and a recycle pump, and wherein the cement and aqueous soap solution are introduced upstream from the first and second homogenizers, whereas the product outlet and the holding vessel are downstream of the second homogenizer.