Layer for cables having improved stress whitening resistance
View Patent ↗The present invention relates to a Insulation layer for cables, a composition and a process thereof, showing improved stress whitening resistance by maintaining good mechanical and electrical properties and being environmental friendly.
1. An insulation layer for cables consisting of a polypropylene composition consisting of
a. a polypropylene base resin (A), which comprises a heterophasic propylene copolymer consisting of
i. an isotactic propylene homo- and/or copolymer as matrix phase having a comonomer content of 0.5 to 10 wt %, based on the total amount of propylene matrix phase, and
ii. a propylene copolymer as dispersed phase having a comonomer content of 20 to 80 wt %, based on the total amount of dispersed phase,
in an amount of 50 to 90 wt % based on the total polypropylene composition; and
b. a polar ethylene polymer (B), in amount of 10 to 50 wt %, based on the total polypropylene composition;
wherein the polar ethylene polymer (B) comprises polar comonomers of C1- to C6-alkyl acrylates, C1- to C6-alkyl methacrylates, acrylic acids, methacrylic acids, or a mixture thereof.
2. Insulation layer for cables according to claim 1 , wherein the propylene copolymer (ii) of the heterophasic propylene copolymer is dispersed in the polypropylene matrix phase; and wherein the propylene copolymer (ii) has an average particle size of less than 1 micrometer.
3. Insulation layer for cables according to claim 1 wherein the amount of propylene copolymer (ii) in the heterophasic propylene copolymer is from 10 to 50 wt. % of the heterophasic propylene copolymer.
4. Insulation layer for cables according to claim 1 wherein the comonomer content of polar ethylene copolymer (B) is from 2 to 40 wt %, based on the total polar ethylene copolymer (B).
5. Insulation layer for cables according to claim 1 wherein the polypropylene composition has a stress whitening intensity of equal to or less than 3 in a three point bending test.
6. Insulation layer for cables according to claim 1 wherein the polypropylene composition has a stress whitening intensity of equal to or less than 3 at a temperature of −40° C. in a cold bend test.
7. Insulation layer for cables according to claim 1 wherein the polypropylene composition shows no crack formation at a temperature of −40° C. in a cold bend test.
8. Insulation layer for cables according to claim 1 wherein the polypropylene composition has a tensile modulus below 1000 MPa.
9. Insulation layer for cables according to claim 1 wherein the polypropylene composition has a strain yield of above 20%.
10. Insulation layer for cables according to claim 1 wherein the polypropylene composition has a maximal peak melting temperature of above 135° C.
11. A process for producing an insulation layer for a cable wherein a polypropylene composition consisting of
a. a polypropylene base resin (A), which comprises a heterophasic propylene copolymer consisting of
i. an isotactic propylene homo- and/or copolymer as matrix phase having a comonomer content of 0.5 to 10 wt %, based on the total amount of propylene matrix phase, and
ii. a propylene copolymer as dispersed phase having a comonomer content of 20 to 80 wt %, based on the total amount of dispersed phase,
in an amount of 50 to 90 wt % based on the total polypropylene composition; and
b. a polar ethylene polymer (B), in amount of 10 to 50 wt %, based on the total polypropylene composition,
is formed into the insulation layer of said cable;
wherein the polar ethylene polymer (B) comprises polar comonomers of C1- to C6-alkyl acrylates, C1- to C6-alkyl methacrylates, acrylic acids, methacrylic acids, or a mixture thereof.
12. A method for producing a cable, comprising extruding a polypropylene composition onto a conductor to form the insulation layer according to claim 1 .
13. A cable comprising an insulation layer according to claim 1 .