Epoxy resin composition for fiber-reinforced composite material
View Patent ↗Provided is an epoxy resin composition for fiber-reinforced composite materials, which is improved in toughness necessary for improving the strength of self-adhesion of a matrix resin for use in a prepreg for a face sheet of a honeycomb panel. The epoxy resin composition, which comprises: an epoxy resin (A); a thermoplastic resin (B); fine solid resin particles (C); and a curing agent (D), is characterized in that the epoxy resin composition after being cured has a morphology in which the epoxy resin (A) and the thermoplastic resin (B) form co-continuous phases, and the fine solid resin particles (C) are dispersed in at least the continuous phase of the epoxy resin (A) in the co-continuous phases.
1. An epoxy resin composition for fiber-reinforced composite materials, comprising:
an epoxy resin (A);
a thermoplastic resin (B);
fine solid resin particles (C); and
a curing agent (D), wherein, in a morphology of the epoxy resin composition after being cured, the epoxy resin (A) and the thermoplastic resin (B) form co-continuous phases, and the fine solid resin particles (C) are dispersed in at least the continuous phase of the epoxy resin (A) in the co-continuous phases and completely dissolved in the epoxy resin (A) at the time of heat curing of the epoxy resin composition, wherein the epoxy resin composition contains, with respect to 100 parts by weight of the epoxy resin (A), 30 to 50 parts by weight of the thermoplastic resin (B) and 2 to 20 parts by weight of the fine solid resin particles (C); wherein the fine solid resin particles (C) is made of a resin having a molecular weight of from 10,000 to 100,000; wherein a fracture toughness value measured according to ASTM D5045-91 after curing of the epoxy resin composition is 1.8 MPa·√m or larger.
2. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the thermoplastic resin (B) has a reactive functional group at its molecular end.
3. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein
the thermoplastic resin (B) is both or any one of polyethersulfone resin particles and polyetherimide resin particles, and
the particle diameter thereof is 200 μm or less.
4. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the fine solid resin particles (C) are made of any one of an epoxy resin, a maleimide resin, a cyanate resin, which are in a solid state at room temperature.
5. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the fine solid resin particles (C) are made of an epoxy resin having a molecular weight of from 10,000 to 35,000.
6. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the fine solid resin particles (C) are made of a bisphenol A-type epoxy resin having an epoxy equivalent of from 1000 to 8000 g/eq.
7. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the fine solid resin particles (C) are made of a phenoxy skeleton-type resin having an epoxy group at its molecular end.
8. The epoxy resin composition for fiber-reinforced composite materials according to claim 7 , wherein the phenoxy skeleton-type resin has a molecular weight of from 50,000 to 60,000.
9. The epoxy resin composition for fiber-reinforced composite materials according to claim 7 , wherein the phenoxy skeleton-type resin has an epoxy equivalent of from 8,000 to 20,000 g/eq.
10. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the fine solid resin particles (C) have a particle diameter of from 0.1 to 2 μm in the morphology of the epoxy resin composition after being cured.
11. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the curing agent (D) is made of any one or both of diaminodiphenylsulfone and a latent curing agent.
12. The epoxy resin composition for fiber-reinforced composite materials according to claim 1 , wherein the epoxy resin composition has a minimum viscosity of from 10 to 150 Pa·s measured in dynamic viscoelasticity measurement at a temperature rise rate of 2° C./minute.
13. A fiber-reinforced prepreg, comprising the epoxy resin composition according to claim 1 as a matrix resin in complex with a reinforcing fiber.
14. The fiber-reinforced prepreg according to claim 13 , wherein the fine solid resin particles (C) have a particle diameter of 100 μm or less.
15. The fiber-reinforced prepreg according to claim 13 , wherein a content of the matrix resin is from 30 to 50 weight %.
16. The fiber-reinforced prepreg according to claim 13 , wherein the reinforcing fiber is carbon fiber.
17. A honeycomb sandwich panel, comprising the fiber-reinforced prepreg according to any one of claim 13 and a honeycomb core that are laminated to each other.
18. The honeycomb sandwich panel according to claim 17 , wherein the honeycomb core is any one selected from the group consisting of aramid honeycombs, aluminum honeycombs, paper honeycombs, and glass honeycombs.