Polymeric material of photosynthetic origin comprising particulate inorganic material
View Patent ↗Disclosed is a new composition of matter comprising a polymeric material of photosynthetic origin having embedded therein small particles of an inorganic material. The composition of matter is particularly suitable for use in processes whereby the polymeric material is converted to fuels in liquid or gas form, and/or to the valuable specialty chemicals. The polymeric material comprises biomass. More specifically, the polymeric material comprises cellulose and at least one of hemicellulose and lignin.
1. A composition of matter comprising a polymeric material of photosynthetic origin having embedded therein particles of an inorganic material, wherein the polymeric material comprises unrefined particulate biomass having a particle size of at least 1 micrometer, wherein the particles of inorganic material have an average particle size in the range of from 40 micrometers to 50 nanometers, wherein the inorganic material is selected from clays, silicas, silica-aluminas, transition metal hydroxides, metal hydroxyl salts, zeolites, cationic layered materials, anionic clays, layered double hydroxides, smectite clays, saponites, sepiolites, and mixtures thereof, wherein the unrefined particulate biomass comprises lignocellulose.
2. The composition of matter of claim 1 wherein the inorganic material is in crystalline or quasi-crystalline form.
3. The composition of claim 1 wherein the particles of inorganic material have an average particle size in the range of from 10 micrometers to 100 nanometers.
4. The composition of claim 1 wherein the inorganic material is an inert inorganic material.
5. The composition of claim 1 , wherein the inorganic material has catalytic properties.
6. The composition of claim 1 for use in the preparation of a bio-oil.
7. The composition of claim 1 for use as a binder.
8. The composition of claim 1 for use as a construction material.
9. The composition of claim 1 wherein the unrefined particulate biomass has a particle size distribution in the range of from 1 micrometer to 100 micrometers.
10. A method for preparing a polymeric material having embedded therein particles of an inorganic material comprising the steps of:
a. contacting a polymeric material of photosynthetic origin with a solution of precursor material to the inorganic particles in a suitable solvent under conditions permitting the solution to penetrate the polymeric material;
b. allowing the solution to penetrate the polymeric material;
c. modifying the conditions to cause the formation of inorganic particulate material from the precursor material,
wherein the polymeric material comprises unrefined particulate biomass having a particle size of at least 1 micrometer,
wherein the particles of inorganic material have an average particle size in the range of from 40 micrometers to 50 nanometers,
wherein the unrefined particulate biomass comprises lignocellulose.
11. The method of claim 10 wherein the solvent comprises water.
12. The method of claim 11 wherein the solvent further comprises a swelling agent.
13. The method of claim 10 wherein the solvent comprises an alcohol.
14. The method of claim 10 wherein the solvent comprises a carboxylic acid.
15. The method of claim 10 , wherein the modification of conditions in step c) comprises a change in temperature, a change in pH, evaporation of the solvent, or a combination thereof.
16. The method of claim 10 , wherein the inorganic material is in crystalline or quasi-crystalline form.
17. A method for preparing a cellulose-containing polymeric material having embedded therein microcrystalline particles of an inorganic material, said method comprising the steps of
a. providing a cellulose-containing polymeric material;
b. providing an aqueous solution of a divalent metal and a trivalent metal;
c. soaking the cellulose polymeric material with the aqueous solution;
d. initiating precipitation of a crystalline inorganic material,
wherein the polymeric material comprises unrefined particulate biomass having a particle size of at least 1 micrometer,
wherein the unrefined particulate biomass comprises lignocellulose.
18. The method of claim 17 wherein the divalent metal is Mg.
19. The method of claim 17 wherein the trivalent metal is Al.
20. The method of claim 17 wherein the crystalline inorganic material is an anionic clay.
21. The method of claim 20 wherein the anionic clay is hydrotalcite.
22. A method for preparing a cellulose-containing polymeric material having embedded therein microcrystalline particles of an inorganic material, said method comprising the steps of
a. providing a cellulose-containing polymeric material;
b. providing an aqueous solution of a cation or anion of a metal capable of forming a particulate inorganic compound;
c. soaking the cellulose polymeric material with the aqueous solution;
d. initiating precipitation of a precursor to a particulate inorganic compound;
e. aging to convert the precursor to the particulate inorganic compound,
wherein the polymeric material comprises unrefined particulate biomass having a particle size of at least 1 micrometer,
wherein the unrefined particulate biomass comprises lignocellulose.
23. The process of claim 22 wherein the cation of step b. is Al 3+ .
24. The process of claim 22 wherein the anion of step b. is Al 2 O 4 2− .