Functionalized olefin interpolymers, compositions and articles prepared therefrom and methods for making the same
The invention provides compositions containing at least one functionalized polyolefin, and in particular, to compositions containing at least one functionalized ethylene interpolymer, which has a melt viscosity less than 50,000 cP at 350° F. (177° C.) and a molecular weight distribution (M w /M n ) from about 1 to 5. The invention also provides adhesive formulations containing the same. The invention also relates to the preparation of the functionalized interpolymers, by reacting, for example, such an ethylene interpolymer with the following: a) at least one unsaturated compound, containing at least one heteroatom, and b) at least one initiator.
1. A composition comprising at least one functionalized functionalized ethylene/α-olefin interpolymer, and wherein the at least one functionalized ethylene interpolymer is formed from a reactive composition comprising an ethylene/α-olefin interpolymer, at least one unsaturated compound containing at least one heteroatom, and at least one initiator, and
wherein the ethylene/α-olefin interpolymer contains greater than 50 mole percent polymerized ethylene monomers, based on total moles polymerizable monomers, and an α-olefin, and
wherein the ethylene/α-olefin interpolymer has a melt viscosity less than 50,000 cP at 350° F. (177° C.), a molecular weight distribution (M w /M n ) from 1 to 5, a melt index (I2) from greater than 300 to 3,500 g/10 min, and a density from 0.865 to 0.895 g/cm 3 , and
wherein the α-olefin is selected from propylene, 1-butene, 1-hexene and 1-octene, and
wherein the at least one functionalized ethylene/α-olefin interpolymer is present in an amount from 15 to 50 weight percent, based on the total weight of the composition, and wherein the composition further comprises from 5 to 35 weight percent of at least one tackifier, based on the total weight of the composition, and from 5 to 35 weight percent of at least one oil or at least one wax, based on the total weight of the composition; and
wherein the at least one functionalized ethylene/α-olefin interpolymer has a number average molecular weight (Mn) from 4,000 to 30,000 g/mole, and
wherein the at least one unsaturated compound is a carbonyl-containing compound, and wherein the weight ratio of the carbonyl-containing compound to the at least one initiator is from 10:1 to 500:1, and wherein the carbonyl-containing compound is present in an amount of at least 1.0 weight percent, based on the total weight of the reactive composition, and the at least one initiator is present in an amount from 500 ppm to 2200 ppm, based on the total weight of the reactive composition.
2. The composition of claim 1 , wherein the carbonyl-containing compound is selected from the group consisting of maleic anhydride, dibutyl maleate, dicyclohexyl maleate, diisobutyl maleate, dioctadecyl maleate, N-phenylmaleimide, citraconic anhydride, tetrahydrophthalic anhydride, bromomaleic anhydride, chloromaleic anhydride, nadic anhydride, methylnadic anhydride, alkenylsuccinic anhydride, maleic acid, fumaric acid, diethyl fumarate, itaconic acid, citraconic acid, crotonic acid, esters thereof, imides thereof, salts thereof, and Diels-Alder adducts thereof.
3. The composition of claim 1 , wherein the ethylene/α-olefin interpolymer has at least one melting temperature from 50° C. to 90° C.
4. The composition of claim 1 , wherein the ethylene/α-olefin interpolymer contains an Rv, a ratio of terminal vinyl groups to the sum of all unsaturation, from 0.01 to 0.4, as determined by 1 H NMR.
5. The composition of claim 1 , wherein the carbonyl-containing compound is maleic anhydride, and wherein the weight ratio of the maleic anhydride to the initiator is from 10:1 to 50:1.
6. The composition of claim 1 , wherein the ethylene/α-olefin interpolymer has a molecular weight distribution from about 1 to 3.
7. The composition of claim 1 , wherein the at least one functionalized ethylene/α-olefin interpolymer has a weight average molecular weight (Mw) from 8,000 to 60,000 g/mole.
8. The composition of claim 1 , wherein the at least one functionalized ethylene/α-olefin interpolymer has a density from 0.86 g/cm 3 to 0.90 g/cm 3 .
9. The composition of claim 1 , wherein the at least one initiator is present in an amount from 1000 ppm to 2000 ppm.
10. The composition of claim 1 , wherein the ethylene/α-olefin interpolymer has a melt index (I2) from greater than 400 g/10 min.
11. An article comprising at least one component formed from the composition of claim 1 .
12. An article comprising wood and at least one component formed from the composition of claim 1 .