Electrophotographic photoreceptor, image-forming apparatus, and electrophotographic cartridge
View Patent ↗An electrophotographic photoreceptor having high sensitivity and hardly affected by the transfer in an electrophotographic process is provided. The electrophotographic photoreceptor includes an undercoat layer containing metal oxide particles and a binder resin and a photosensitive layer disposed on the undercoat layer, wherein the metal oxide particles have a volume average particle diameter of 0.1 μm or less and a 90% cumulative particle diameter of 0.3 μm or less which are measured by a dynamic light-scattering method in a liquid of the undercoat layer dispersed in a solvent mixture of methanol and 1-propanol at a weight ratio of 7:3, and the photosensitive layer contains a binder resin having an ester bond.
1. An electrophotographic photoreceptor comprising an undercoat layer comprising metal oxide particles and a binder resin on an electroconductive support, and a photosensitive layer disposed on the undercoat layer, wherein
the metal oxide particles comprise secondary particles having a volume average particle diameter of 0.1 μm or less and a 90% cumulative particle diameter of 0.3 μm or less which are measured by a dynamic light-scattering method in a liquid of the undercoat layer dispersed in a solvent mixture of methanol and 1-propanol at a weight ratio of 7:3; and
the photosensitive layer comprises a binder resin having an ester bond.
2. The electrophotographic photoreceptor according to claim 1 , wherein the binder resin having an ester bond is polycarbonate or polyester.
3. The electrophotographic photoreceptor according to claim 2 , wherein the polyester is polyarylate.
4. The electrophotographic photoreceptor according to claim 1 , wherein the binder resin having an ester bond is produced by interfacial polymerization.
5. The electrophotographic photoreceptor according to claim 1 , wherein the photosensitive layer comprises a compound represented by Formula (I):
wherein, in Formula (I),
Ar 1 to Ar 6 each independently represents an aromatic moiety, an aromatic moiety having a substituent, an aliphatic moiety, or an aliphatic moiety having a substituent;
X represents an organic moiety;
R 1 to R 4 each independently represents an organic group having a hydrazone structure;
n 1 represents 1 or 2; and
n 2 to n 6 each represents an integer of 0 to 2.
6. The electrophotographic photoreceptor according to claim 5 , wherein, in Formula (I), all of Ar 1 to Ar 6 are benzene moieties.
7. An image-forming apparatus comprising:
eletrophotographic photoreceptor according to claim 1 ;
charging means for charging the electrophotographic photoreceptor;
image exposure means for forming an electrostatic latent image by conducting image exposure to the charged electrophotographic photoreceptor;
development means for developing the electrostatic latent image with toner; and
transfer means for transferring the toner to a transfer object.
8. An electrophotographic cartridge comprising:
an eletrophotographic photoreceptor according to claim 1 ; and
at least one selected from charging means for charging the electrophotographic photoreceptor, image exposure means for forming an electrostatic latent image by conducting image exposure to the charged electrophotographic photoreceptor, development means for developing the electrostatic latent image with toner, transfer means for transferring the toner to a transfer object, fixing means for fixing the toner transferred to the transfer object, and cleaning means for recovering the toner adhering to the electrophotographic photoreceptor.