Fiber-reinforced thermoplastic resin molded article
View Patent ↗Provided is a fiber-reinforced thermoplastic resin molded article, which contains reinforcing fibers having a given flattened cross-sectional profile, in which the fiber length distribution of the reinforcing fibers is shifted on the side of long fibers, and which is excellent in mechanical strength, heat resistance, dimensional accuracy such as warpage resistance, and surface appearance.
1. A fiber-reinforced thermoplastic resin molded article of a thermoplastic resin composition comprising from 70 to 35% by weight of a thermoplastic resin (A), and from 30 to 65% by weight of reinforcing fibers (B) of which the cross section is flattened to have a degree of flatness, as expressed by the formula mentioned below, of at least 2.3, wherein the thermoplastic resin (A) is polyamide resin containing at least 20% by weight of MX nylon or polyester resin, and the weight-average fiber length of the reinforcing fibers in the molded article is at least 1 mm:
Degree of flatness=major diameter of reinforcing fiber ( a )/minor diameter of reinforcing fiber ( b ).
2. The fiber-reinforced thermoplastic resin molded article of claim 1 , wherein the degree of flatness of the reinforcing fibers (B) is from 2.3 to 5.
3. The fiber-reinforced thermoplastic resin molded article of claim 1 , wherein the weight-average fiber length is from 1 to 10 mm.
4. The fiber-reinforced thermoplastic resin molded article of claim 1 , wherein the proportion of the reinforcing fibers having a fiber length of at least 1 mm in the molded article is at least 30% by weight of all the reinforcing fibers.
5. The fiber-reinforced thermoplastic resin molded article of claim 1 , wherein the cross-sectional profile of the reinforcing fibers (B) is oval.
6. The fiber-reinforced thermoplastic resin molded article of claim 1 , which contains a polybutylene terephthalate resin and/or a polyethylene terephthalate resin as the polyester resin.
7. The fiber-reinforced thermoplastic resin molded article of claim 1 , which contains a polybutylene terephthalate resin having a limiting viscosity, as measured in a 1/1 (by weight) mixed solution of phenol and 1,1,2,2-tetrachloroethane at 30° C., of from 0.3 to 1.2 dl/g, and having a titanium content of at most 80 ppm, as the polyester resin.
8. The fiber-reinforced thermoplastic resin molded article of claim 1 , which is produced according to an injection-molding method or an extrusion-molding method using pellets prepared by coating the reinforcing fiber with the thermoplastic resin followed by cutting into pellets having a length of at least 3 mm, and wherein the reinforcing fiber is reinforcing fiber rovings.
9. A method for producing a fiber-reinforced thermoplastic resin molded article of claim 1 , which comprises performing injection-molding or extrusion-molding of pellets prepared by coating the reinforcing fiber with the thermoplastic resin followed by cutting into pellets having a length of at least 3 mm, and wherein the reinforcing fiber is reinforcing fiber rovings.