Olefin polymerisation catalyst
View Patent ↗The present invention relates to particulate olefin polymerization catalyst components comprising an alkaline earth metal, a compound of a transition metal and an electron donor, characterized in that the catalyst particle size distribution of the catalyst component is essentially monomodal and has a SPAN value below 1.2, where SPAN is defined as: (Particle diameter at 90% cumulative size)−(Particle diameter at 10% cumulative size)/(Particle diameter at 50% cumulative size). The particulate olefin polymerisation catalyst components of the present invention are provided by a process which comprises preparing a solution of a complex of an alkaline earth metal and an electron donor by reacting a compound of said metal with said electron donor or a precursor thereof in an organic liquid reaction medium, reacting said complex in the solution form with a compound of a transition metal to produce a dispersion, wherein the dispersed phase predominantly contains the alkaline earth metal in said complex, and solidifying said dispersed phase to obtain said catalyst component, and is characterized in that a second organic liquid medium is added to the reactor after mixing the alkaline earth metal complex with the transition metal compound.
1. A particulate polymerisation catalyst component comprising an alkaline earth metal, a compound of a transition metal, an electron donor and an Al compound of general formula AlR 3-n X n , wherein each R stands independently for a straight chain or branched alkyl or alkoxy group having 1 to 20 carbon atoms, X independently represents halogen and n stands for 0, 1, 2 or 3
wherein the particle size distribution of the catalyst component is essentially monomodal and has a SPAN value below 1.2, where SPAN is defined as:
(Particle diameter at 90% cumulative size)−(Particle diameter at 10% cumulative size)/(Particle diameter at 50% cumulative size),
where the term 90%/10%/50% cumulative size represents the particle size threshold at which 90%/10%/50% of the cumulated amount of particles are below that size.
2. A particulate polymerisation catalyst component according to claim 1 , wherein the SPAN value of the catalyst particle size distribution is in the range of 0.5 to 1.2.
3. A particulate polymerisation catalyst component according to claim 1 , wherein the particles of the catalyst component have a median particle size of more than 30 μm and mode of more than 30 μm.
4. A particulate polymerisation catalyst component according to claim 1 , wherein the particles of the catalyst component have a median particle size of 30 to 60 μm and mode of 30 to 65 μm.
5. A particulate polymerisation catalyst component according to claim 1 , wherein the particles of the catalyst component have a median particle size of 40 to 50 μm, and mode of 40 to 55 μm.
6. A particulate polymerisation catalyst component according to claim 1 , wherein the alkaline earth metal is magnesium.
7. A particulate polymerisation catalyst component according to claim 1 , wherein the transition metal is a Group 4, 5 or 6 metal.
8. A particulate polymerisation catalyst component according to claim 1 , wherein the transition metal is Ti, Cu, Fe, Co, Ni and/or Pd.
9. A particulate polymerisation catalyst component according to claim 1 , wherein the compound of a transition metal is TiCl 4 .
10. A particulate polymerisation catalyst component according to claim 1 , wherein the electron donor is an aromatic carboxylic acid ester.
11. A particulate polymerisation catalyst component according to claim 1 , wherein the electron donor is di(ethylhexyl) phthalate.
12. A particulate polymerisation catalyst component according to claim 1 , wherein the Al content of the particles is from 0.1 to 0.7%, by weight of the catalyst particles.
13. A particulate polymerisation catalyst component according to claim 1 ,
wherein R stands independently for a straight chain or branched alkyl or alkoxy group having 1 to 10 carbon atoms.
14. A particulate polymerisation catalyst component according to claim 1 , wherein R stands independently for a straight chain or branched alkyl or alkoxy group having 1 to 6 carbon atoms.
15. A particulate polymerisation catalyst component according to claim 1 , wherein X independently represents chloride.