Recording medium
View Patent ↗Provided is an optical recording medium comprising a substrate and a reflective layer, a first dielectric layer, a recording layer, a second dielectric layer and a light-transmission layer formed in this order on the substrate. The recording layer is decomposable by heat at a time of recording to achieve recording of the optical recording medium, and the optical recording medium further comprises a third dielectric layer between the second dielectric layer and the light-transmission layer.
1. An optical recording medium comprising a substrate and a reflective layer, a first dielectric layer, a recording layer, a second dielectric layer and a light-transmission layer formed in this order on the substrate,
wherein the recording layer is decomposable by heat at a time of recording to achieve recording of the optical recording medium,
wherein the optical recording medium further comprises a third dielectric layer between the second dielectric layer and the light-transmission layer, and
wherein the recording layer comprises a material A that decomposes at an arrival temperature of the recording layer by heat at a time of recording; and a material B that undergoes a chemical reaction at the arrival temperature of the recording layer by heat at the time of recording,
wherein the third dielectric layer has a hardness greater than the hardness of the second dielectric layer.
2. The optical recording medium according to claim 1 , wherein the refractive index of the third dielectric layer is lower than the refractive index of the second dielectric layer at a wavelength of light used for optical recording.
3. The optical recording medium according to claim 1 , wherein the third dielectric layer comprises an oxide of at least one element selected from the group consisting of Si, Y, Ce, Zr, Nb, Ta, Zn, Al, In and Sn; a nitride of at least one element selected from the group consisting of Si, Ge and Al; or a mixture thereof.
4. The optical recording medium according to claim 1 , wherein the third dielectric layer comprises a mixture of an oxide of Si and a nitride of Si.
5. The optical recording medium according to claim 1 , wherein the hardness of the third dielectric layer is at least 8 GPa according to a nano-indentation method.
6. The optical recording medium according to claim 1 , wherein the difference between the refractive index of the third dielectric layer and the refractive index of the light-transmission layer is at most 0.5 at a wavelength of light used for optical recording.
7. The optical recording medium according to claim 1 , which further comprises at least one layer selected from the group consisting of an antidiffusion layer, an underlayer, a protection coat layer, and a close contact layer.
8. The optical recording medium according to claim 7 , wherein the close contact layer is used as the first dielectric layer or the second dielectric layer.
9. The optical recording medium according to claim 1 , wherein each of the material A and the material B independently is at least one nitride, at least one oxide, or a mixture thereof.
10. The optical recording medium according to claim 1 , wherein the material A is an oxide of a metal or an oxide of a semiconductor.
11. The optical recording medium according to claim 1 , wherein the material A is an oxide of at least one element selected from the group consisting of Ir, Au, Ag, and Pt.
12. The optical recording medium according to claim 1 , wherein the material A is a nitride of a metal or a nitride of a semiconductor.
13. The optical recording medium according to claim 1 , wherein the material A is a nitride of at least one element selected from the group consisting of Cr, Mo, W, Fe, Ge, and Sn.
14. The optical recording medium according to claim 1 , wherein the material B is a nitride of a metal or a nitride of a semiconductor.
15. The optical recording medium according to claim 1 , wherein the material B is a nitride of at least one element selected from the group consisting of Ti, Zr, Hg, V, Nb, Ta, Al, and Si.
16. The optical recording medium according to claim 1 , wherein the material B is an oxide of a metal or an oxide of a semiconductor.
17. The optical recording medium according to claim 1 , wherein the material B is an oxide of at least one element selected from the group consisting of Zn, Al, Y, Zr, Ti, Nb, Ni, Mg, and Si.