IP Library Granted Patent US 8,173,256
Granted Patent B2
US 8,173,256 · App. 12/307,863 · Granted May 8, 2012

Aromatic polyamide fiber, a method for producing the same, and protective clothing material comprising the same

Assignee: Teijin Techno Products Limited
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Quick Facts
Patent No.
US 8,173,256
App. No.
12/307,863
Granted
May 8, 2012
Kind
B2
Abstract

An aromatic polyamide fiber comprising an aromatic polyamide containing a structural repeating unit of the following formula (1), and a structural repeating unit of the following repeating unit (2) in an amount of 30 mol % or more to the whole amount of the aromatic polyamide structural units, the fiber having strength of 20 cN/dtex or more and modulus of elongation of 500 cN/dtex or more: wherein Ar 1 and Ar 2 each independently represent an unsubstituted or substituted divalent aromatic group.

Claims (11)

1. An aromatic polyamide fiber comprising an aromatic polyamide consisting of a structural repeating unit of the following formula (1), and a structural repeating unit of the following repeating unit (2) in an amount of 30 mol % or more to the whole amount of the aromatic polyamide structural units, the fiber having strength of 20 to 26.9 cN/dtex and modulus of elongation of 500 to 900 cN/dtex:

wherein Ar 1 represents an unsubstituted or substituted divalent aromatic group, and Ar 2 represents an unsubstituted phenylene group;

wherein the fiber comprises filaments having a fineness of 0.5 to 2.2 dtex.

2. A protective clothing material comprising a layered product of a single kind or plural kinds of fiber cloths, wherein the fiber cloth is comprised of the aromatic polyamide fiber as claimed in claim 1 .

3. A method for producing an aromatic polyamide fiber, comprising extruding an aromatic polyamide solution containing a structural repeating unit of the following formula (1), and a structural repeating unit of the following repeating unit (2) in an amount of 30 mol % or more to the whole amount of the aromatic polyamide structural units from a spinning nozzle, coagulating the solution in an NMP aqueous solution having a concentration of from 10 to 50% by weight at a temperature of from 20 to 50° C., drawing the resulting fiber by 1.3 to 2.5 times in an NMP aqueous solution having a concentration of from 30 to 80% by weight at a temperature of from 20 to 50° C., and then heat-treating the resulting fiber:

wherein Ar 1 and Ar 2 each independently represent an unsubstituted or substituted divalent aromatic group,

wherein said method produces an aromatic polyamide fiber as claimed in claim 1 .

4. The method for producing an aromatic polyamide fiber as claimed in claim 3 , wherein the heat treatment temperature is from 300 to 550° C.

5. The method for producing an aromatic polyamide fiber as claimed in claim 3 or 4 , wherein tensile strength of the aromatic polyamide fiber is 21.5 to 26.9 cN/dtex, and initial modulus thereof is 570 to 900 cN/dtex.

6. The aromatic polyamide fiber as claimed in claim 1 , wherein the fiber comprises filaments having a fineness of 0.5 to 1.7 dtex.

7. The aromatic polyamide fiber as claimed in claim 1 , wherein the fiber comprises filaments having a fineness of 0.5 to 1.4 dtex.

Assignments (2)
MERGER Recorded Dec 3, 2012
From: TEIJIN TECHNO PRODUCTS LIMITED
To: TEIJIN LIMITED
Reel/Frame 029393/0416 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 7, 2009
From: MARUMOTO, YASUHIRO; ISHIHARA, SHIGERU
To: TEIJIN TECHNO PRODUCTS LIMITED
Reel/Frame 022070/0537 →
Continuity (1)
Related Publication 20090239052A1 · Sep 24, 2009