Structure for electrochemical device to improve safety and electrochemical device comprising the same
Disclosed is a sealed structure for an electrochemical device having a hollow space therein, further comprising a material generating gases via thermal decomposition in the hollow space. Also, disclosed is an electrochemical device comprising a cathode, an anode, a separator, an electrolyte, a casing for the device, and the structure for the electrochemical device.
1. A structure suitable for use in an electrochemical device comprising:
(A) a hollow cylindrical tube formed of a polymer, and containing a material for generating inert gases via thermal decomposition in a hollow space thereof;
(B) a first member formed of a polymer and sealing one end of the hollow cylindrical tube; and
(C) a second member formed of a polymer or a metal and sealing the other end of the hollow cylindrical tube;
wherein the polymer of the hollow cylindrical tube has a higher melting point than the melting point of the polymer of the first member or the polymer or the metal of the second member, and
wherein the material for generating inert gases via thermal decomposition is at least one compound selected from the group consisting of organic peroxides, carbonate compounds, azo compounds, hydrazide compounds and carbazide compounds.
2. The structure as claimed in claim 1 , wherein either or both of the first member and the second member melt at a temperature higher than a normal drive temperature of the device or at a voltage higher than 4.3 V.
3. The structure as claimed in claim 1 , wherein each of the polymer forming the first member and the polymer forming the second member is at least one polymer independently selected from the group consisting of silicone resins, acrylic resins, urethane resins, epoxy resins, rubber, polyethylene, polypropylene, polybutene, polyacetaldehyde, polyformaldehyde, polypropylene oxide, polymethyl methacrylate, polyvinylidene chloride, polyvinyl fluoride and polyvinylidene fluoride.
4. A structure suitable for use in an electrochemical device comprising:
(A) a hollow cylindrical tube formed of a polymer or a metal, and containing a material for generating inert gases via thermal decomposition in a hollow space thereof, having at least one opening on a surface thereof and sealed at both ends thereof; and
(B) a polymer member for sealing the opening;
wherein the polymer or the metal of the hollow cylindrical tube has a higher melting point than the melting point of the polymer member, and
wherein the material for generating inert gases via thermal decomposition is at least one compound selected from the group consisting of organic peroxides, carbonate compounds, azo compounds, hydrazide compounds and carbazide compounds.
5. The structure as claimed in claim 4 , wherein the polymer member melts at a temperature higher than a normal drive temperature of the device or at a voltage higher than 4.3V.
6. The structure as claimed in claim 4 , wherein the polymer member is formed of at least one polymer selected from the group consisting of silicone resins, acrylic resins, urethane resins, epoxy resins, rubber, polyethylene, polypropylene, polybutene, polyacetaldehyde, polyformaldehyde, polypropylene oxide, polymethyl methacrylate, polyvinylidene chloride, polyvinyl fluoride and polyvinylidene fluoride.