Polysiloxane composition
View Patent ↗A polysiloxane composition having high transparency, while being excellent in heat resistance and light resistance is provided. The polysiloxane composition is composed of (A) a polysiloxane which is a polysiloxane compound having a polyhedral skeleton having 6 to 24 silicon atoms in its molecule and which has at least one group containing a hydrolyzable silyl group bonded to a Si atom constituting the polyhedral skeleton, and (B) a photoacid generator. The hydrolyzable silyl group is preferably an alkoxysilyl group.
1. A polysiloxane composition comprising:
(A) a polysiloxane which is a polysiloxane compound having a polyhedral skeleton and which has at least one group containing a hydrolyzable silyl group bonded to a Si atom constituting the polyhedral skeleton; and
(B) a photoacid generator,
wherein the hydrolyzable silyl group in component (A) is selected from the group consisting of an alkoxysilyl group, an acetoxysilyl group and a halogenated silyl group.
2. The polysiloxane composition according to claim 1 , wherein the polysiloxane compound (A) having the polyhedral skeleton is a polysiloxane compound having a polyhedral skeleton having 6 to 24 Si atoms in its molecule.
3. The polysiloxane composition according to claim 1 , wherein the hydrolyzable silyl group in the component (A) is an alkoxysilyl group.
4. The polysiloxane composition according to claim 3 , wherein the group containing a hydrolyzable silyl group in the component (A) is an alkoxysilylethyl group or an alkoxysilylpropyl group.
5. The polysiloxane composition according to claim 3 , wherein the group containing a hydrolyzable silyl group in the component (A) is at least one group containing an alkoxysilyl group selected from the group consisting of an (alkoxysilylethyl)dimethylsilyl group, an (alkoxysilylethyl)diphenylsilyl group, an (alkoxysilylpropyl)dimethylsilyl group, and an (alkoxysilylpropyl)diphenyl group.
6. The polysiloxane composition according to claim 1 , wherein the polysiloxane compound (A) having the polyhedral skeleton is obtained by reacting a polyhedral-structured polysiloxane compound having functional groups that can react with components (1) and (2) below,
(1) a compound having one functional group that can react with the functional groups of the polyhedral-structured polysiloxane compound and at least one hydrolyzable silyl group, and
(2) a compound that has two or more functional groups that can react with the functional groups of the polyhedral-structured polysiloxane compound.
7. The polysiloxane composition according to claim 1 , wherein the polyhedral-structured polysiloxane compound in the component (A) is a polyhedral-structured silylated silicic acid compound.
8. The polysiloxane composition according to claim 6 , wherein each of the functional groups that can react with components (1) and (2) in the polyhedral-structured polysiloxane compound is an alkenyl group or a hydrosilyl group.
9. The polysiloxane composition according to claim 6 , wherein the hydrolyzable silyl group in the component (1) is an alkoxysilyl group.
10. The polysiloxane composition according to claim 6 , wherein the functional groups that can react with the polyhedral-structured polysiloxane compound in the component (2) are bonded to both ends of the compound.
11. The polysiloxane composition according to claim 6 , wherein the component (2) is at least one selected from the group consisting of polyalkylenes, polyisobutylene, polyesters, polybutyl acrylate, polyethers, polyamides, polyimides, and polysiloxanes.
12. The polysiloxane composition according to claim 6 , wherein a reaction between the polyhedral-structured polysiloxane compound and the components (1) and (2) is conducted by a hydrosilylation reaction.
13. The polysiloxane composition according to claim 1 , wherein the photoacid generator is an onium salt.
14. An optical member comprising the polysiloxane composition according to claim 1 .