Welded steel pipe for high strength line pipe superior in low temperature toughness and method of production of the same
View Patent ↗The present invention provides high strength welded steel pipe for line pipe inexpensive in cost and superior in low temperature toughness, and a method of production of the same, produced by forming a base material steel plate containing, by mass %, C: 0.010 to 0.050%, Si: 0.01 to 0.50%, Mn: 0.50 to 2.00%, S: 0.0001 to 0.0050%, and Ti: 0.003 to 0.030%, limiting Al to 0.020% or less and Mo to less than 0.10%, having a carbon equivalent Ceq of 0.30 to 0.53 and a crack susceptibility parameter Pcm of 0.10 to 0.20, comprised of polygonal ferrite and residual bainite of an area rate of 20% or less, and having an effective crystal grain size of 20 μm or less, into a pipe shape, then seam welding it and making the effective crystal grain size of the heat affected zone 150 μm or less.
1. High strength welded steel pipe for line pipe superior in low temperature toughness, the high strength welded steel pipe comprising steel pipe obtained by seam welding a base material steel plate formed into a pipe shape, wherein said base material steel plate comprises, by mass %,
C: 0.010 to 0.050%,
Si: 0.01 to 0.50%,
Mn: 0.50 to 2.00%,
S: 0.0001 to 0.0050%,
Ti: 0.003 to 0.030%,
O: 0.0001 to 0.0080%,
B: 0.0003 to 0.0030%, and
a balance of iron and unavoidable impurities, wherein P, Al, and Mo are present at most as impurities, and
P is limited to 0.050% or less,
Al is limited to 0.020% or less, and
Mo is limited to less than 0.10%, and wherein
Ceq found from the formula,
C eq =C+Mn/6+(Ni+Cu)/15+(Cr+Mo+V)/5,
is 0.30 to 0.53,
Pcm found by the formula,
P cm =C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B,
is 0.10 to 0.20, wherein C, Si, Mn, Ni, Cu, Cr, Mo, V, and B are the amounts of the individual elements in mass %, and wherein
a metal structure of said base material steel plate has a polygonal ferrite area ratio of no more than 20%,
a bainite area ratio of at least 80%,
an effective crystal grain size of no more than 20 μm, and
an effective crystal grain size in a weld heat affected zone of no more than 150 μm.
2. The high strength welded steel pipe as set forth in claim 1 , wherein the base material steel plate has a thickness of 25 to 40 mm.
3. The high strength welded steel pipe as set forth in claim 1 , wherein said base material steel plate has a tensile strength measured using a circumferential direction of said steel pipe as the tension direction of 600 to 800 MPa.
4. The high strength welded steel pipe as set forth in claim 1 , wherein said base material steel plate further comprises, by mass %, one or both of
Cu: 0.05 to 1.50% and
Ni: 0.05 to 5.00%.
5. The high strength welded steel pipe as set forth in claim 1 , wherein said base material steel plate further comprises, by mass %, one or more of
Cr: 0.02 to 1.50%,
V: 0.010 to 0.100%,
Nb: 0.001 to 0.200%,
Zr: 0.0001 to 0.0500%, and
Ta: 0.0001 to 0.0500%.
6. The high strength welded steel pipe as set forth in claim 1 , wherein said base material steel plate further comprises, by mass %, one or more of
Mg: 0.0001 to 0.0100%,
Ca: 0.0001 to 0.0050%,
REM: 0.0001 to 0.0050%,
Y: 0.0001 to 0.0050%,
Hf: 0.0001 to0.0050%,
Re: 0.0001 to 0.0050%, and
W: 0.01 to 0.50%.
7. The high strength welded steel pipe as set forth in claim 1 , wherein the steel pipe further comprises a weld metal, the weld material comprising, by mass %,
C: 0.010 to 0.100%,
Si: 0.01 to 0.50%,
Mn: 1.0 to 2.0%,
Al: 0.001 to 0.100%,
Ti: 0.003 to 0.050%,
O: 0.0001 to 0.0500%, and a balance of iron and unavoidable impurities, wherein P and S are present at most as impurities, and
P is limited to 0.010% or less and
S is limited to 0.010% or less.
8. The high strength welded steel pipe as set forth in claim 7 , said weld metal further comprising, by mass %, one or both of
Ni: 0.2 to 3.2% and
Cr+Mo+V:0.2 to 2.5%.
9. A method of production of high strength welded steel pipe for line pipe superior in low temperature toughness, the method comprising:
adding deoxidizing agents, comprising Si and Mn, before casting the steel,
then adding Ti to form a steel composition
casting the steel composition, forming a steel slab,
hot rolling the steel slab, forming a steel plate, and
forming the steel plate into a pipe shape having seam portions, and
seam welding the seam portions; wherein, after adding the Ti, the steel comprises, by Mass %,:
C: 0.010 to 0.050%,
Si: 0.01 to 0.50%,
Mn: 0.50 to 2.00%,
S: 0.0001 to 0.0050%,
Ti: 0.003 to 0.030%,
O: 0.0001 to 0.0080%,
B: 0.0003 to 0.0030%, and
a balance of iron and unavoidable impurities, wherein P, Al, and Mo are present at most as impurities, and
P is limited to 0.050% or less,
Al is limited to 0.020% or less, and
Mo is limited to less than 0.10%, and wherein
Ceq found from the formula
C eq =C+Mn/6+(Ni+Cu)/15+(Cr+Mo+V)/5
is 0.30 to 0.53,
Pcm found from the formula
P cm =C+Si/30+(Mn+Cu 30 Cr)/20+Ni/60+Mo/15+V/10+5B
is 0.10 to 0.20, wherein C, Si, Mn, Ni, Cu, Cr, Mo, V, and B are the amounts of the individual elements in mass %.
10. The method of production of high strength welded steel pipe as set forth in claim 9 , further comprising heating said steel slab to a temperature of at least 1000° C., hot rolling the heated steel to obtain a rolling ratio in the pre-recrystallization temperature region of 2.5 or more, and water cooling to a temperature of no more than 600° C.
11. The method of production of high strength welded steel pipe as set forth in claim 9 , further comprising forming said steel plate into a pipe shape by a UO process, welding seam portions from inner and outer surfaces by submerged arc welding using welding wire and a firing type or molten type flux, and then expanding the pipe.
12. The method of production of high strength welded steel pipe as set forth in claim 11 , wherein said submerged arc welding provides a heat input of 4.0 to 10.0 kJ/mm.
13. The method of production of high strength welded steel pipe as set forth in claim 9 , further comprising heat treating the seam weld zone.
14. The method of production of high strength welded steel pipe as set forth in claim 13 , further comprising heat treating the seam weld zone in a temperature range of 300° to 500° C.
15. The method of production of high strength welded steel pipe as set forth in claim 9 , wherein said base material steel plate further comprises, by mass %, one or both of Cu: 0.05 to 1.50% and Ni: 0.05 to 5.00%.
16. The method of production of high strength welded steel pipe as set forth in claim 9 , wherein said base material steel plate further comprises, by mass %, one or more of Cr: 0.02 to 1.50%, V: 0.010 to 0.100%, Nb: 0.001 to 0.200%, Zr: 0.0001 to 0.0500%, and Ta: 0.0001 to 0.0500%.
17. The method of production of high strength welded steel pipe as set forth in claim 9 , wherein said base material steel plate further comprises, by mass %, one or more of Mg: 0.0001 to 0.0100%, Ca: 0.0001 to 0.0050%, REM: 0.0001 to 0.0050%, Y: 0.0001 to 0.0050%, Hf: 0.0001 to 0.0050%, Re: 0.0001 to 0.0050%, and W: 0.01 to 0.50%.