Method for producing martensitic stainless steel pipe
View Patent ↗A martensitic stainless steel pipe, which comprises specified quantities of C, Si, Mn, P, S, Cr, Ni, Al, N, Cu, Ti, V, Mo, Nb, B and Ca, and the balance being Fe and impurities, has satisfactory toughness at a high strength of 650 MPa or more by yield strength and also excellent hot workability. Therefore, it can be used as a high-strength martensitic stainless steel pipe for carbon dioxide gas corrosion resistant use, to be used in oil and/or gas well environments containing no hydrogen sulfide but carbon dioxide gas. This high-strength martensitic stainless steel pipe is an inexpensive martensitic stainless steel pipe, which does not require an addition of large quantities of expensive elements such as Ni and Mo, and moreover does not require the control of the content of P to a value less than 0.010% by mass.
1. A method for producing a high-strength martensitic stainless steel pipe which comprises:
heating the steel pipe, which is made by use of the martensitic steel, having a chemical composition comprising by mass percent, C: 0.18 to 0.22%, Si: 0.1 to 0.5%, Mn: 0.40 to 1.00%, P: 0.011 to 0.018%, S: 0.003% or less, Cr: 11.50 to 13.50%, Ni: 0.5% or less, Al: 0.0005 to 0.003%, N: 0.012 to 0.040%, Cu: 0.25% or less, Ti: 0.05% or less, V: 0.02 to 0.18%, Mo: 0 to 0.05%, Nb: 0 to 0.009%, B: 0.0010% or less, and Ca: 0.0050% or less, with the balance being Fe and impurities, as the material and cooled to room temperature by atmospheric cooling or air cooling, at a temperature T 1 , which exists in the temperature range of 930 to 980 degrees C., for 5 to 30 minutes;
then cooling the steel pipe from the temperature T 1 to a temperature T 2 , which exists in the temperature range of 600 to 350 degrees C., at a cooling rate of 1 to 40 degrees C./sec;
successively cooling the steel pipe from the temperature T 2 to a temperature T 3 , which exists in the temperature range of 300 to 150 degrees C., and from the temperature range lower than the temperature T 3 to room temperature at cooling rates of less than 1 degrees C./sec and of 5 to 40 degrees C./sec, respectively; and,
performing a bend straightening treatment at a straightener outlet temperature of 510 degrees C. or higher successively to tempering treatment at 610 to 750 degrees C.
2. A method for producing a high-strength martensitic stainless steel pipe which comprises:
heating the steel pipe, which is made by use of the martensitic steel, having a chemical composition comprising by mass percent, C: 0.18 to 0.21%, Si: 0.1 to 0.5%, Mn: 0.40 to 0.70%, P: 0.011 to 0.018%, S: 0.003% or less, Cr: 11.50 to 13.50%, Ni: 0.5% or less, Al: 0.0005 to 0.003%, N: 0.012 to 0.032%, Cu: 0.25% or less, Ti: 0.05% or less, V: 0.04 to 0.18%, Mo: 0 to 0.05%, Nb: 0.002 to 0.009%, B: 0.0010% or less, and Ca: 0.0050% or less, with the balance being Fe and impurities, as the material and cooled to room temperature by atmospheric cooling or air cooling, at a temperature T 1 , which exists in the temperature range of 930 to 980 degrees C., for 5 to 30 minutes;
then cooling the steel pipe from the temperature T 1 to a temperature T 2 , which exists in the temperature range of 600 to 350 degrees C., at a cooling rate of 1 to 40 degrees C./sec;
successively cooling the steel pipe from the temperature T 2 to a temperature T 3 , which exists in the temperature range of 300 to 150 degrees C., and from the temperature range lower than the temperature T 3 to room temperature at cooling rates of less than 1 degrees C./sec and of 5 to 40 degrees C./sec, respectively; and,
performing a bend straightening treatment at a straightener outlet temperature of 510 degrees C. or higher successively to tempering treatment at 610 to 750 degrees C.