IP Library Granted Patent US 8,778,099
Granted Patent B2
US 8,778,099 · App. 12/316,020 · Granted Jul 15, 2014

Conversion process for heat treatable L1

Inventor: Awadh B. Pandey (Jupiter, FL)
Assignee: United Technologies Corporation
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Quick Facts
Patent No.
US 8,778,099
App. No.
12/316,020
Granted
Jul 15, 2014
Kind
B2
Abstract

A method for producing high strength aluminum alloy containing L1 2 intermetallic dispersoids by using gas atomization to produce powder that is then consolidated into L1 2 aluminum alloy billets or by casting the alloy into molds to produce L1 2 aluminum alloy billets or by casting the alloy into directly useable parts.

Claims (40)

1. A method for forming a heat treatable high strength aluminum alloy containing L1 2 dispersoids, comprising the steps of:

preparing an aluminum alloy composition consisting of:

at least one first element selected from the group consisting of about 0.1 to about 6.0 weight percent erbium, about 0.1 to about 10.0 weight percent thulium, about 0.1 to about 15.0 weight percent ytterbium, and about 0.1 to about 12.0 weight percent lutetium;

at least one second element selected from the group consisting of about 0.1 to about 4.0 weight percent gadolinium, about 0.1 to about 4.0 weight percent yttrium, about 0.05 to about 2.0 weight percent titanium, and about 0.05 to about 1.0 weight percent niobium to the aluminum alloy;

at least one third element selected from the group consisting of about 4 to about 18 weight percent silicon, about 1 to about 2 weight percent lithium, and about 3.5 to about 6.5 weight percent copper; and

the balance substantially aluminum;

melting the composition to form an alloy;

casting the alloy to form a solid product; and

heat treating the alloy to form L1 2 dispersoids.

2. The method of claim 1 , wherein the solid product is selected from the group comprising:

a usable part;

a billet for deformation processing; and

a powder.

3. The method of claim 1 , wherein casting comprises pouring the melted alloy into a mold.

4. The method of claim 1 , wherein casting comprises rapid solidification with cooling rates greater than 10 3 ° C./second by gas atomization formation of aluminum alloy powder.

5. The method of claim 4 , wherein the gas atomization process is an inert gas atomization process comprising:

inert gas consisting of at least one of argon, nitrogen and helium;

melt superheat temperature from about 100° F. (38° C.) to about 300° F. (149° C.);

gas pressure of about 50 psi (0.35 MPa) to about 750 psi (5.2 MPa);

metal flow rate of about from 0.5 pounds (0.23 kg) per minute to 25 pounds (11.3 kg) per minute; and

gas pressure to metal weight ratio is about 100 psi/lb/min (1.52 MPa/kg/min) to about 1500 psi/lbs/min (22.8 MPa/kg/min).

6. The method of claim 5 , wherein oxygen is introduced during atomization such that the oxygen content of the powder is between 1 ppm and 2000 ppm and the hydrogen content is about 1 ppm to about 1000 ppm.

7. The method of claim 1 , wherein the heat treating comprises:

solution heat treatment at about 800° F. (426° C.) to about 1100° F. (593° C.) for about thirty minutes to four hours;

quenching; and

aging at a temperature of about 200° F. (93° C.) to about 600° F. (315° C.) for about two to forty eight hours.

8. The method of claim 7 , wherein heat treatment results in formation of L1 2 Al 3 X strengthening dispersoids to form in the aged alloy.

9. A method for producing a heat treatable high strength aluminum alloy billet containing L1 2 dispersoids, comprising the steps of:

(a) forming a melt consisting of:

at least one first element selected from the group comprising about 0.1 to about 4.0 weight percent erbium, about 0.1 to about 6.0 weight percent thulium, about 0.2 to about 8.0 weight percent ytterbium, and about 0.2 to about 8.0 weight percent lutetium;

at least one second element selected from the group comprising about 0.2 to about 2.0 weight percent gadolinium, about 0.2 to about 2.0 weight percent yttrium, about 0.1 to about 1.0 weight percent titanium, and about 0.1 to about 0.75 weight percent niobium;

at least one third element selected from the group consisting of about 4 to about 18 weight percent silicon, about 1 to about 2 weight percent lithium, and about 3.5 to about 6.5 weight percent copper; and

the balance substantially aluminum;

(b) solidifying the melt to form a solid body; and

(c) heat treating the solid body to form L1 2 dispersoids.

10. The method of claim 9 , wherein the heat treating comprises:

solution heat treatment at about 800° F. (426° C.) to about 1100° F. (593° C.) for about thirty minutes to four hours;

quenching; and

aging at a temperature of about 200° F. (93° C.) to about 600° F. (315° C.) for about two to forty eight hours.

11. The method of claim 9 , wherein solidifying comprises rapid solidification process with cooling rates greater than about 10 3 ° C./second by gas atomization formation of aluminum alloy powder.

Assignments (4)
CHANGE OF NAME Recorded Jul 27, 2023
From: RAYTHEON TECHNOLOGIES CORPORATION
To: RTX CORPORATION
Reel/Frame 064714/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE AND REMOVE PATENT APPLICATION NUMBER 11886281 AND ADD PATENT APPLICATION NUMBER 14846874. TO CORRECT THE RECEIVING PARTY ADDRESS PREVIOUSLY RECORDED AT REEL: 054062 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF ADDRESS. Recorded Mar 4, 2021
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 055659/0001 →
CHANGE OF NAME Recorded Sep 4, 2020
From: UNITED TECHNOLOGIES CORPORATION
To: RAYTHEON TECHNOLOGIES CORPORATION
Reel/Frame 054062/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2009
From: PANDEY, AWADH B.
To: UNITED TECHNOLOGIES CORPORATION
Reel/Frame 022341/0988 →
Continuity (1)
Related Publication 20100139815A1 · Jun 10, 2010