Direct epoxidation process using improved catalyst
View Patent ↗A supported catalyst and a catalyst mixture, useful for the direct epoxidation of olefins, are disclosed. The supported catalyst comprises a noble metal, lead, and a carrier that has been treated by contacting with nitric acid. The catalyst mixture comprises a titanium or vanadium zeolite and the supported catalyst. The invention also includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst mixture. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.
1. A process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of a titanium or vanadium zeolite and a supported catalyst comprising palladium, lead and a carrier that has been treated by contacting with nitric acid.
2. The process of claim 1 wherein the titanium or vanadium zeolite is a titanium silicalite.
3. The process of claim 1 wherein the olefin is a C 2 -C 6 olefin.
4. The process of claim 1 wherein the reaction is performed in the presence of a solvent selected from the group consisting of alcohols, ketones, nitriles, water, liquid CO 2 , and mixtures thereof.
5. The process of claim 1 wherein the carrier is selected from the group consisting of titania, zirconia, niobia, silica, tantalum oxide, titania-silica, zirconia-silica, niobia-silica, and mixtures thereof.
6. A supported catalyst comprising palladium, lead, and a carrier that has been treated by contacting with nitric acid.
7. The supported catalyst of claim 6 wherein the carrier is selected from the group consisting of titania, zirconia, niobia, silica, tantalum oxide, titania-silica, zirconia-silica, niobia-silica, and mixtures thereof.
8. The supported catalyst of claim 7 wherein the carrier is titania.
9. The supported catalyst of claim 8 wherein the titania is contacted with nitric acid prior to introduction of the noble metal and the lead.
10. A catalyst mixture comprising a titanium or vanadium zeolite and a supported catalyst comprising palladium, lead, and a carrier that has been treated by contacting with nitric acid.
11. The catalyst mixture of claim 10 wherein the titanium zeolite is a titanium silicalite.
12. The catalyst mixture of claim 11 wherein the titanium silicalite is TS-1 or Ti-MWW.
13. The catalyst mixture of claim 10 wherein the carrier is selected from the group consisting of titania, zirconia, niobia, silica, tantalum oxide, titania-silica, zirconia-silica, niobia-silica, and mixtures thereof.