IP Library Granted Patent US 7,972,193
Granted Patent B2
US 7,972,193 · App. 12/317,595 · Granted Jul 5, 2011

Non-conductive balloons and methods of producing same

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Quick Facts
Patent No.
US 7,972,193
App. No.
12/317,595
Granted
Jul 5, 2011
Kind
B2
Abstract

The present invention relates to articles and methods for producing non-latex balloons with low surface electrical conductivities and an extended product life. In a preferred embodiment, a multilayer composite film having an exposed metallized layer is coated with an elastomeric sealant layer that increases electrical resistivity of the balloon product to greater than 1.0 8 Ohms/sq. The invention relates to articles and methods for producing needed bonds and seal strength required to manufacture non latex balloons. The balloons of this invention have an extended product life because they are more resistant to common defects like pin holing and stress cracks than conventional balloon systems.

Claims (20)

1. A non-latex balloon product comprising, in combination:

a. a core polyester layer having first and second sides;

b. an amorphous polyester layer adhered to the first side of the core polyester layer;

c. a metalized layer adhered to the second side of the core polyester layer where the metalized layer has an exposed side; and

d. a elastomeric sealant layer comprising a melt processable polyolefin overlaying the exposed side of the metalized layer, where the elastomeric sealant layer has bond strength to the metalized layer that is greater than 200 g/in,

wherein the balloon product has a surface electrical resistivity of greater than 1.0 8 Ohms/sq.

2. A non-latex balloon product comprising, in combination:

a. a core polyester layer having first and second sides;

b. an amorphous polyester layer adhered to the first side of the core polyester layer;

c. a metalized layer overlaying on the amorphous polyester layer where the metalized layer has an exposed side; and

d. an elastomeric sealant layer comprising a melt processable polyolefin overlaying the exposed side of the metalized layer, where the elastomeric sealant layer has bond strength to the metalized layer that is greater than 200 g/in;

wherein the balloon product has a surface electrical resistivity of greater than 1.0 8 Ohms/sq.

3. The balloon product of claims 1 or 2 wherein the layers have a measurable thickness and the elastomeric sealant layer is 5 to 75% of the thickness.

4. The balloon product of claims 1 or 2 wherein the elastomeric sealant layer comprises linear low density polyethylene (LLDPE).

5. The balloon product of claims 1 or 2 further characterized in that it can be inflated to greater than one atmosphere of pressure with air or lighter than air gas.

6. The balloon product of claims 1 or 2 wherein the elastomeric sealant layer has a thickness in the range from about 5 to about 50 microns.

7. The balloon product of claims 1 or 2 wherein the elastomeric sealant layer has a seal strength to itself that is greater than 2000 g/in.

8. The balloon product of claims 1 or 2 wherein the elastomeric sealant layer has a recovery of elongation preferably 40 to 100%.

9. The balloon product of claim 2 characterized in that the core polyester layer comprises polyethylene terephthalate (PET).

10. The balloon product of claim 2 wherein the amorphous polyester layer and the metalized layer has a dry bonding strength greater than 300 g/in.

Assignments (24)
SECURITY INTEREST Recorded May 2, 2025
From: ANAGRAM INTERNATIONAL LLC,
To: CIBC BANK USA
Reel/Frame 071010/0684 →
CHANGE OF NAME Recorded Apr 10, 2024
From: CELEBRATION BIDCO, LLC
To: ANAGRAM INTERNATIONAL, LLC
Reel/Frame 067070/0271 →
SECURITY INTEREST Recorded Jan 11, 2024
From: COMPUTERSHARE TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
To: ANAGRAM INTERNATIONAL, INC.
Reel/Frame 066106/0372 →
RELEASE OF SECURITY INTEREST Recorded Jan 11, 2024
From: WILMINGTON SAVINGS FUND SOCIETY, FSB, AS COLLATERAL TRUSTEE
To: ANAGRAM INTERNATIONAL, INC.
Reel/Frame 066106/0359 →
RELEASE OF SECURITY INTEREST Recorded Jan 11, 2024
From: GLAS TRUST COMPANY LLC
To: ANAGRAM INTERNATIONAL, INC.
Reel/Frame 066106/0366 →
TERMINATION AND RELEASE OF SECURITY INTEREST Recorded Jan 10, 2024
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: ANAGRAM INTERNATIONAL, INC.
Reel/Frame 066269/0824 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 2, 2024
From: ANAGRAM INTERNATIONAL, INC.
To: CELEBRATION BIDCO, LLC
Reel/Frame 065995/0102 →
SECURITY INTEREST Recorded Jan 2, 2024
From: CELEBRATION BIDCO, LLC
To: GLAS AMERICAS LLC, AS COLLATERAL AGENT
Reel/Frame 065995/0087 →
SECURITY INTEREST Recorded Jan 2, 2024
From: CELEBRATION BIDCO, LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 065997/0450 →
SECURITY INTEREST Recorded Nov 17, 2023
From: ANAGRAM INTERNATIONAL, INC.
To: GLAS TRUST COMPANY LLC
Reel/Frame 065596/0549 →
SECURITY INTEREST Recorded Oct 3, 2023
From: ANKURA TRUST COMPANY, LLC
To: COMPUTERSHARE TRUST COMPANY, NATIONAL ASSOCIATION
Reel/Frame 065111/0970 →
SECURITY INTEREST Recorded Sep 19, 2023
From: ANKURA TRUST COMPANY, LLC
To: WILMINGTON SAVINGS FUND SOCIETY, FSB
Reel/Frame 064946/0826 →
SECURITY INTEREST Recorded May 8, 2021
From: ANAGRAM INTERNATIONAL, INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 056179/0230 →
SECURITY INTEREST Recorded Jul 31, 2020
From: ANAGRAM INTERNATIONAL, INC.
To: ANKURA TRUST COMPANY, LLC
Reel/Frame 053365/0291 →
SECURITY INTEREST Recorded Jul 31, 2020
From: ANAGRAM INTERNATIONAL, INC.
To: ANKURA TRUST COMPANY, LLC
Reel/Frame 053365/0246 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS, RECORDED AT REEL 028652, FRAME 0979 Recorded Aug 19, 2015
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: AMSCAN, INC; AM-SOURCE, INC.; ANAGRAM INTERNATIONAL, INC.; M&D INDUSTRIES, INC.; TRISAR, INC.
Reel/Frame 036396/0632 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS, RECORDED AT REEL 028652, FRAME 0714 Recorded Aug 19, 2015
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: AMSCAN, INC.; AM-SOURCE, INC.; ANAGRAM INTERNATIONAL, INC; M&D INDUSTRIES, INC.; TRISAR
Reel/Frame 036396/0913 →
GRANT OF SECURITY INTEREST IN US PATENTS [TERM LOAN SECURITY AGREEMENT] Recorded Jul 27, 2012
From: AMSCAN, INC.; AM-SOURCE, INC.; ANAGRAM INTERNATIONAL, INC.; M&D INDUSTRIES, INC. (F/K/A M&D BALLOONS, INC. AND D/B/A M&D FLEXOGRAPHIC PRINTERS, INC.); TRISAR, INC.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS
Reel/Frame 028652/0979 →
GRANT OF SECURITY INTEREST IN US PATENTS [ABL SECURITY AGREEMENT] Recorded Jul 27, 2012
From: AMSCAN, INC.; AM-SOURCE, INC.; ANAGRAM INTERNATIONAL, INC.; M&D INDUSTRIES, INC. (F/K/A M&D BALLOONS, INC. AND D/B/A M & D FLEXOGRAPHIC PRINTERS, INC.); TRISAR, INC.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS
Reel/Frame 028652/0714 →
RELEASE OF SECURITY INTEREST Recorded Jul 27, 2012
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, SUCCESSOR BY MERGER TO WELLS FARGO RETAIL FINANCE, LLC
To: AMSCAN, INC.; ANAGRAM INTERNATIONAL, INC.; M&D INDUSTRIES, INC.
Reel/Frame 028659/0469 →
RELEASE OF SECURITY INTEREST Recorded Jul 27, 2012
From: CREDIT SUISSE AG, AS COLLATERAL AGENT
To: AMSCAN, INC.; ANAGRAM INTERNATIONAL, INC.; M&D INDUSTRIES, INC.
Reel/Frame 028659/0593 →
PATENT SECURITY AGREEMENT Recorded Dec 3, 2010
From: AMSCAN INC.; ANAGRAM INTERNATIONAL, INC.; M&D INDUSTRIES, INC.
To: CREDIT SUISSE AG
Reel/Frame 025441/0457 →
SECURITY INTEREST Recorded Aug 18, 2010
From: AMSCAN INC.; ANAGRAM INTERNATIONAL, INC.; M&D INDUSTRIES, INC.
To: WELLS FARGO RETAIL FINANCE, LLC
Reel/Frame 024850/0459 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 9, 2009
From: SARNSTROM, TODD; ANSOLABEHERE, PAUL; BORCHARDT, DEAN; SWANSON, ANDREW; CERNOHOUS, JEFFREY J.; FATICA, MICHAEL; CHICARELLA, GIANFRANCO
To: ANAGRAM INTERNATIONAL, INC.
Reel/Frame 022935/0992 →