Microporous polyolefin multi layer film and preparing method thereof
View Patent ↗The present invention relates to a multi-layered microporous polyolefin film for a battery separator and a method for preparing the same. The microporous multi-layered film of the present invention has a characteristics to have both the low shutdown temperature conferred by the polyethylene and the high melt fracture temperature conferred by the polypropylene and heat-resistant filler. In addition, it has the high strength and stability conferred by the micropores prepared under wet process and the high permeability and high strength conferred by the macropores prepared under dry process. Therefore, this multi-layered film can be used effectively to manufacture a secondary battery with high capacity and high power.
1. A microporous polyolefin multilayer film comprising a polyethylene layer comprising a polyethylene having a melting temperature of 125° C. or higher, and a polypropylene and heat-resistant layer comprises 20-60 wt % of propylene having a melting temperature of 160° C. or higher and 80-40 wt % of a heat-resistant resin having a melting temperature of 170° C. or higher, wherein the film has a thickness of 9-30 μm, a piercing strength of 0.15 N/μm or more, a permeability of 1.5×10 -5 Darcy or more and a melt fracture temperature of 170° C. or higher, in which the pores of the polyethylene layer are micropores that are fabricated by stretching and extracting after separating the phase of polyethylene and the diluent and have an average size of 0.1 μm or smaller; and the pores of the polypropylene and heat-resistant layer are macropores that are fabricated by cracking of the interface between the polypropylene and heat-resistant resin and have an average size of 1-50 μm.
2. The microporous polyolefin multilayer film according to claim 1 , where in the polyethylene is single or combined polyethylene comprising ethylene only or ethylene and C3-C8 α-olefin and having a melting temperature of 125° C. or higher; the polypropylene is single or combined polypropylene comprising propylene only or propylene, ethylene and C4-C8 α-olefin having a melting temperature of 160° C. or higher; and the heat-resistant resin having a melting temperature of 170° C. or higher is a resin selected among polyvinylidene fluoride, polymethylpentene, polyethylene terephthalate, polycarbonate, polyester, polyvinyl alcohol, polyacrylonitrile and polymethylene oxide.
3. The microporous polyolefin multilayer film according to claim 1 , wherein the polyethylene layer occupies more than 50% of the total thickness and the polypropylene and heat-resistant layer has a thickness of at least 1 μm.
4. The microporous polyolefin multilayer film according to claim 1 , wherein the film has a thickness of 9-30 μm, a piercing strength of 0.2 N/μm or more and a permeability of 2.5×10 −5 −10.0×10 −5 Darcy.
5. The microporous polyolefin multilayer film according to claim 1 , wherein the polypropylene and heat resistant layer further comprises an inorganic material that has an average particle size of 0.01-5 μm and is selected among silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), calcium carbonate (CaCO 3 ), titanium dioxide (TiO 2 ), SiS 2 , SiPO 4 , MgO, ZnO, BaTiO 3 , natural or organically modified clay, and a mixture thereof.