Method and apparatus for the production of high tenacity polyolefin sheet
View Patent ↗A process for the production of virtually full density polyolefin suitable for further processing by drawing to form a high tenacity, highly oriented polyolefin sheet comprising: a) feeding a metered amount of polyolefin powder into the nip between two vertically stacked and heated calender rolls through application of the polyolefin powder to the apex of the topmost of the two heated calender rolls; b) rolling the powder through the nip until a coherent sheet of polyolefin sheet is produced: and c) once a coherent polyolefin sheet exits the nip adjusting the temperature in the nip to obtain specific tensile and elongation properties. Apparatus for the performance of such a process is also described.
1. A process for the production of high tenacity, highly oriented polyolefin sheet having a high heat of fusion comprising:
a) feeding a metered amount of a ultra high molecular weight polyethylene (UHMWPE) powder to an apparatus comprising:
i) a pair of vertically oriented, counter rotating heated calender rolls defining a nip therebetween and including a top and a bottom heated calender roll, the top heated calender roll having an outer surface and an apex; and
ii) a metering mechanism for feeding a metered amount of the polyolefin powder to the apex wherefrom the polyolefin powder softens and agglomerates on the outer surface of the top roll and is drawn on the outer surface of the top roll to the nip by rotation of the top roll from the apex of the top roll surface to the nip;
b) rolling the polymer powder through the nip under these conditions until a coherent polyolefin sheet is produced;
c) once a coherent polyolefin sheet exits the nip, adjusting the temperature in the nip to a temperature between 12 degrees C. lower to 8 degrees C. greater than the temperature required to initiate the onset of melting for the particular polyolefin powder being processed as determined by differential scanning calorimetry; and
d) drawing the coherent polyolefin sheet under controlled tension at a temperature of between 140 and 158° C. to produce a high tenacity, highly oriented polyolefin sheet having a high heat of fusion.
2. The process of claim 1 wherein the UHMWPE powder exhibits a crystallinity of greater than 80% as determined by differential scanning calorimetry, a heat of fusion equal to or greater than 220 joules/gram, and low levels of entanglement.
3. The process of claim 2 wherein the temperature in step c is between 130° C. and 145° C.
4. The process of claim 2 wherein the operating temperature in step c is between 8 degrees C. lower and 4 degrees C. higher than the onset of melt for the particular UHMWPE powder being processed as determined by differential scanning calorimetry.
5. The process of claim 4 wherein the operating temperature in step c is between 2 degrees lower C and 2 degrees C. higher than the onset of melt for the particular UHMWPE powder being processed as determined by differential scanning calorimetry.
6. The process of claim 3 wherein the counter rotating calender rolls rotate at a rate of between 2 and 12 meters/minute.
7. The process of claim 1 wherein drawing is performed in-line and continuously with the formation of the coherent sheet and said sheet includes a heat of fusion of greater than 243 joules/gram, a density of 0.95 to 0.98 g/cc, a tensile modulus of 1200 to 1800 g/d, and an elongation of 1.6 to 2.0 percent.