Melt spinning blends of UHMWPE and HDPE and fibers made therefrom
View Patent ↗Compositions that are intimate blends of ultrahigh molecular weight polyethylene and high-density polyethylene (HDPE), and which are melt spinnable. The compositions include certain quasi-spherical particles. Also disclosed is a method of melt spinning from such compositions and the multi-filament fibers produced thereby. The fibers of the invention are useful in a variety of applications.
1. A method of producing a high strength polyethylene multi-filament fiber comprising the steps of:
a) forming an intimate blend of a composition comprising about 50 to about 90 percent by weight of an UHMWPE having an intrinsic viscosity of from about 6 to about 15 dl/g; about 10 to about 50 percent by weight of an HDPE having an intrinsic viscosity of from about 0.75 to about 3 dl/g; and about 0.1 to about 1 percent by weight of a material comprising quasi-spherical particles having a weight average particle size of from about 0.05 to about 10 micrometers and a Mohs' hardness of at least about 4, said particles comprising at least 50 percent by weight of inorganic non-metallic materials; wherein the polyethylene portion of said blend has an intrinsic viscosity of from about 2.4 to about 5 dl/g and a ratio of weight average to number average molecular weight of at least about 7, with all said intrinsic viscosities being measured in decalin at 135° C. by ASTM D1601-99;
b) spinning a melt of said blend through a spinneret at an apparent shear rate at least about 250 sec −1 to form a plurality of substantially smooth melt filaments;
c) stretching said melt filaments to a stretch ratio of x:1;
d) rapidly quenching said melt filaments to form solid filaments; and
e) stretching said solid filaments to a stretch ratio of y:1; wherein y is at least about 2 and the product x times y is at least about 10.
2. The method of claim 1 , wherein said the polyethylene portion of said blend has a ratio of weight average to number average molecular weight at least about 10.
3. The method of claim 1 , wherein said intimate blend comprises about 65 to about 85 percent by weight of said UHMWPE and about 15 to about 35 percent by weight of said HDPE.
4. The method of claim 1 , wherein said particles comprise titanium dioxide.
5. The method of claim 4 , wherein said titanium dioxide is in the anatase crystalline form.
6. The method of claim 1 , wherein said intimate blend is formed in the molten state in an intermeshing, co-rotating twin screw extruder.
7. The method of claim 6 , wherein said intimate blend is passed in the molten state from said twin screw extruder to a melt pump and therefrom to a spinneret.