Method of increasing filler content in papermaking
View Patent ↗The invention provides a method of producing paper with a higher proportion of mineral filler particles than is otherwise be possible without the expected loss in paper strength. The method allows for the use of the greater amount of filler particles by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a strength additive. The strength additive holds the cellulose fibers together tightly and is not wasted on the filler particles. The method is particularly effective when the filler particles are a PCC-GCC blend and when the GCC particles are coated with the adherence preventing coating.
1. A method of papermaking having an increased filler content, the method comprising the steps of:
providing a blend of filler particles, at least one strength additive, and cellulose fiber stock,
pre-treating the filler particles with a composition of matter,
combining the filler particles with the cellulose fiber stock after the filler particles have been pre-treated,
treating the combination with at least one strength additive, and
forming a paper mat from the combination,
wherein at least 10% of the filler particles are precipitated calcium carbonate and at least 10% of the filler particles are ground calcium carbonate,
the cellulose fiber stock comprises a plurality of cellulose fibers and water, and
the composition of matter enhances the performance of the strength additive in the paper mat.
2. The method of claim 1 in which the paper mat is formed by removing some of the water from the combination.
3. The method of claim 1 in which at least some of the calcium carbonate is in one form selected from the list consisting of: undispersed calcium carbonate, dispersed slurry calcium carbonate, chalk, and any combination thereof.
4. The method of claim 1 in which at least a portion of the calcium carbonate is in a dispersed slurry calcium carbonate form, the dispersed slurry calcium carbonate further comprising at least one item selected from: polyacrylic acid polymer dispersants, sodium polyphosphate dispersants, Kaolin clay slurry, and any combination thereof.
5. The method of claim 1 in which the blend of filler particles is 50% ground calcium carbonate and 50% precipitated calcium carbonate.
6. The method of claim 1 in which the composition of matter is a coagulant.
7. The method of claim 1 in which the composition of matter is a coagulant selected from the list consisting of: inorganic coagulants, organic coagulants, condensation polymerization coagulants, and any combination thereof.
8. The method of claim 1 in which the composition of matter is a coagulant having a molecular weight range of between 200 and 1,000,000.
9. The method of claim 1 in which the composition of matter is a coagulant selected from the list consisting of: alum, sodium aluminate, polyaluminum chlorides, aluminum chlorohydroxide, aluminum hydroxide chloride, polyaluminum hydroxychloride, sulfated polyaluminum chlorides, polyaluminum silica sulfate, ferric sulfate, ferric chloride, epichlorohydrin-dimethylamine (EN-DMA), EPI-DMA ammonia crosslinked polymers, polymers of ethylene dichloride and ammonia, polymers of ethylene dichloride, polymers of dimethylamine, condensation polymers of multifunctional diethylenetriamine, condensation polymers of multifunctional tetraethylenepentamine, condensation polymers of multifunctional hexamethylenediamine condensation polymers of multifunctional ethylenedichloride, melamine polymers, formaldehyde resin polymers, cationically charged vinyl addition polymers, and any combination thereof.
10. The method of claim 1 in which the composition of matter is an AcAm/DADMAC copolymer.
11. The method of claim 1 in which the strength additive is glyoxylated Acrylamide/DADMAC copolymer.
12. The method of claim 1 in which the ratio of strength additive relative to the solid portion of the paper mat is 0.3 to 5 kg of strength additive per ton of paper mat.
13. The method of claim 1 in which at least some of the GCC particles are treated with the composition of matter.
14. The method of claim 1 in which none of the PCC particles are treated with the composition of matter.
15. The method of claim 1 in which the strength additive is a cationic starch.
16. The method of claim 1 in which the paper mat has a solid portion and the filler particles in the paper mat comprise more than 50% of the combined mass of the solid portion of the paper mat.
17. The method of claim 1 in which the strength additive and the composition of matter carry the same charge.
18. The method of claim 1 in which the blend of filler particles further comprises one item selected from the list consisting of: organic pigment, inorganic pigment, clay, talc, titanium dioxide, alumina trihydrate, barium sulfate, magnesium hydroxide, and any combination thereof.