LIQUID CRYSTAL DISPLAY DEVICE AND A METHOD OF MANUFACTURING THE SAME
Disclosed herein is a liquid crystal display device including two sheets of substrates, a liquid crystal layer sealed between the two sheets of substrates, and a retardation layer provided on the liquid crystal layer side in one of the two sheets of substrates, wherein the retardation layer has a structure in which polymerizable liquid crystal monomers are three-dimensionally cross-linked, and a retardation R(450) for a wavelength of 450 nm and a retardation R(550) for a wavelength of 550 nm fulfill a relationship of R(450)/R(550)≦1.
1 . A liquid crystal display device including:
two sheets of substrates;
a liquid crystal layer sealed between said two sheets of substrates; and
a retardation layer provided on said liquid crystal layer side in one of said two sheets of substrates, wherein said retardation layer has a structure in which polymerizable liquid crystal monomers are three-dimensionally cross-linked, and a retardation R(450) for a wavelength of 450 nm and a retardation R(550) for a wavelength of 550 nm fulfill a relationship of R(450)/R(550)≦1.
2 . The liquid crystal display device according to claim 1 , wherein
a plurality of pixels each having a transmissive display portion and a reflective display portion set therein are disposed and formed between said two sheets of substrates; and
said retardation layer is formed in a pattern in each of said pixels so as to correspond to said reflective display portion.
3 . A method of manufacturing a liquid crystal display device including the steps of
forming a retardation layer on a first substrate;
disposing a second substrate so as to face a side of a formation surface of said retardation layer in said first substrate; and
filling and sealing a liquid crystal layer between said first substrate and said second substrate, said method of manufacturing a liquid crystal display device, when said retardation layer is formed; comprising the steps of:
applying a liquid solution containing therein polymerizable liquid crystal monomers onto an orientation surface of said first substrate to form a retardation layer formation film;
performing orientation processing for said retardation layer formation film;
three-dimensionally cross-linking said polymerizable liquid crystal monomers contained said retardation layer formation film for which the orientation processing is performed to cure said polymerizable liquid crystal monomers; and
obtaining said retardation layer in which a retardation R(450) for a wavelength of 450 nm and a retardation R(550) for a wavelength of 550 nm fulfill a relationship of R(450)/R(550)≦1.
4 . The method of manufacturing a liquid crystal display device according to claim 3 , wherein 50% or more of said polymerizable liquid crystal monomers in said retardation layer formation film have two or more acrylate groups at their ends.
5 . The method of manufacturing a liquid crystal display device according to claim 3 , wherein in the three-dimensionally cross-linking of said polymerizable liquid crystal monomers, said polymerizable liquid crystal monomers are three-dimensionally cross-linked in an exposed portion by carrying out pattern exposure for said retardation layer formation film; and
said manufacturing method further comprises the step of:
pattering said retardation layer formation film so as to leave said exposed portion by performing development processing for said retardation layer formation film.
6 . A liquid crystal display device including:
two sheets of substrates;
a liquid crystal layer sealed between said two sheets of substrates;
a reflective material layer provided on a side of said liquid crystal layer in one of said two sheets of substrates; and
a retardation layer formed in a pattern above said reflective material layer,
wherein said reflective material layer is entirely covered with said retardation layer.
7 . The liquid crystal display device according to claim 6 , wherein
a plurality of pixels each having a transmissive display portion and a reflective display portion set therein are disposed and formed between said two sheets of substrates; and
said reflective material layer and said retardation layer are each formed in a pattern in each of said pixels so as to correspond to said reflective display portion.
8 . The liquid crystal display device according to claim 6 , wherein said reflective material layer is made of a metallic material.