Methods for reducing fluid loss of a viscoelastic surfactant gel into a subterranean formation
Methods and compositions of treating formations using viscoelastic treatment fluids are provided that reduce the amount of fluid loss to the formations due to the lack of polymer backbone in the viscoelastic treatment fluids. The methods and compositions of treating formations include a fluid loss additive that includes a copolymer that includes a hydrophilic monomeric unit and a first anchoring monomeric unit.
1. A method of fracturing a subterranean formation penetrated by a well bore comprising the steps of:
a. combining (i) a viscoelastic surfactant gel essentially free of a polymer and (ii) a fluid loss additive comprising a copolymer comprising a hydrophilic monomeric unit and a first anchoring monomeric unit based upon at least one of N-vinylformamide, N,N-diallylacetamide, or a mixture thereof to render a fracturing fluid;
b. pumping the fracturing fluid into the well bore at a pressure above the fracture gradient of the subterranean formation;
c. fracturing the subterranean formation and inhibiting the passage of the viscoelastic surfactant gel in the fracturing fluid from passing through pore throats of the subterranean formation, thereby reducing the rate of fluid loss of the viscoelastic surfactant gel into the subterranean formation.
2. The method of claim 1 , wherein the copolymer further comprises a second anchoring monomeric unit based on at least one of dimethyldiallyl ammonium chloride, ammonium or alkali metal salts of acrylic acid, or a mixture thereof.
3. The method of claim 1 , wherein the copolymer further comprises a filler monomeric unit based on acrylamide, methylacrylamide, or a mixture thereof.
4. The method of claim 1 , wherein the hydrophilic monomeric unit is based on an ammonium or alkali metal salt of acrylamidomethylpropanesulfonic acid, acrylamidomethylpropanesulfonic acid, acrylic acid, acrylate salt, or a mixture thereof.
5. The method of claim 1 , wherein the fluid loss additive is a present in a range of about 0.1 gpt to about 60 gpt.
6. The method of claim 1 , wherein the fracturing fluid is introduced into the well bore at a temperature of up to about 300° F.
7. The method of claim 1 , wherein the viscoelastic surfactant gel fluid further comprises an anionic surfactant.
8. The method of claim 1 , wherein the amount of first anchoring monomeric unit in the copolymer is between from about 2 to about 30% by weight.
9. The method of claim 1 , wherein:
(i) the amount of fluid loss additive in the fracturing fluid is the range of about 0.1 gpt to about 60 gpt; and
(ii) the pH of the fracturing fluid is buffered in the range from about 6.5 to 10.0.
10. A method of reducing fluid loss of a viscoelastic surfactant gel into a subterranean formation which comprises pumping into a well bore penetrating a subterranean formation at a pressure above the fracture gradient of the subterranean formation a fracturing fluid prepared by combining:
(i) a viscoelastic surfactant gel essentially free of a polymer; and
(ii) a fluid loss additive comprising a copolymer comprising a hydrophilic monomeric unit and a first anchoring monomeric unit based upon at least one of N-vinylformamide, N,N-diallylacetamide, or a mixture thereof
and fracturing the subterranean formation, wherein the amount of fluid loss of the viscoelastic surfactant gel in the fracturing fluid into the subterranean formation is reduced by the presence of the fluid loss additive in the fracturing fluid.
11. The method of claim 10 , wherein the amount of fluid loss additive in the fracturing fluid is in the range of about 0.1 gpt to about 60 gpt.
12. The method of claim 10 , wherein the fracturing fluid is introduced into the well bore at a temperature of up to about 300° F.
13. The method of claim 10 , wherein the viscoelastic surfactant gel comprises an anionic surfactant.
14. The method of claim 10 , wherein the copolymer further comprises a second anchoring monomeric unit based on at least one of dimethyldiallyl ammonium chloride, ammonium or alkali metal salts of acrylic acid, or a mixture thereof.
15. The method of claim 10 , wherein the copolymer further comprises a filler monomeric unit based on acrylamide, methylacrylamide, or a mixture thereof.
16. The method of claim 10 , wherein the hydrophilic monomeric unit is based on an ammonium or alkali metal salt of acrylamidomethylpropanesulfonic acid, acrylamidomethylpropanesulfonic acid, acrylic acid, acrylate salt, or a mixture thereof.
17. A method of fracturing a subterranean formation penetrated by a well bore which comprises:
pumping into the subterranean formation at a pressure above the pressure gradient of the subterranean formation a fracturing fluid prepared by combining:
(i) a viscoelastic surfactant gel essentially free of a polymer; and
(ii) a fluid loss additive comprising a copolymer comprising a hydrophilic monomeric unit and a first anchoring monomeric unit based upon at least one of N-vinylformamide, N,N-diallylacetamide, or a mixture thereof; and
reducing the rate of fluid loss of the viscoelastic surfactant gel in the fracturing fluid into the subterranean formation by the presence of the fluid loss additive in the fracturing fluid.
18. The method of claim 17 , wherein the viscoelastic surfactant of the viscoelastic surfactant gel is an alkyl sarcosinate or the combination of a cationic surfactant and an anionic surfactant.
19. The method of claim 17 , wherein the viscoelastic surfactant of the viscoelastic surfactant gel is N,N,N,trimethyl-1-octadecammonium chloride and sodium xylene sulfonate.
20. The method of claim 17 , wherein the copolymer further comprises a second anchoring monomeric unit based on at least one of dimethyldiallyl ammonium chloride, ammonium or alkali metal salts of acrylic acid, or a mixture thereof.