Emission treatment system
An emission treatment system and method for remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams are described. The emission treatment system has an oxidation catalyst upstream of a soot filter upstream from a NOx reducing catalyst.
1. A method of treating an exhaust stream from a diesel engine, the exhaust stream comprising NOx and particulate matter, the method comprising:
disposing within an exhaust stream containing NO 2 a diesel oxidation catalyst (DOC), wherein the DOC comprises platinum and palladium dispersed on a refractory metal oxide which is mixed with a zeolite component, the diesel oxidation catalyst producing no NO 2 in the exhaust stream exiting the diesel oxidation catalyst by increasing the ratio of Pd:Pt;
disposing a catalyzed soot filter comprising platinum downstream from the diesel oxidation catalyst, the catalyzed soot filter having a plurality of longitudinally extending passages bounded by longitudinally extending walls, the passages comprising inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the catalyst soot filter comprising a catalyst composition on the walls, the catalyst soot filter effective to optimize the ratio of NO to NO 2 exiting the filter;
disposing a selective catalytic reduction catalyst downstream from the catalyzed soot filter; and passing the exhaust stream from the diesel engine through the diesel oxidation catalyst, the catalyzed soot filter and the selective catalytic reduction catalyst,
wherein the NO/NO 2 ratio exiting the catalyst soot filter is between 0.6 and 1.4, wherein control of the NO to NO 2 ratio of the exhaust gas flowing into the SCR is provided by using the combination of the DOC and the CSF.
2. The method of claim 1 , further comprising disposing a reductant injection system between the catalyzed soot filter and the selective catalytic reduction catalyst, the reductant injection system periodically adding a reductant into the exhaust stream exiting the catalyzed soot filter.
3. The method of claim 2 , further comprising disposing an ammonia oxidation catalyst subsequent to the selective catalytic reduction catalyst.
4. The method of claim 1 , further comprising metering a reductant into the exhaust stream prior to selective catalytic reduction catalyst.
5. The method of claim 4 , further comprising oxidizing residual reductant subsequent to the selective catalytic reduction catalyst.