Golf ball with high moisture barrier properties
View Patent ↗Golf balls including at least one layer formed from high moisture barrier nanocomposite compositions that have increased moisture resistance and generally include a nanocomposite including an intercalated clay and at least one resin having a barrier property, a polyolefin resin, and a compatilizer.
1. A golf ball comprising a core and a cover, wherein the cover is formed from a composition comprising:
a nanocomposite comprising an intercalated clay and at least one resin having a barrier property; and
a polyolefin resin; and
a compatibilizer, wherein the compatibilizer comprises a compatibilizing agent comprising a polymer functionalized with at least one amine group, hydroxy group, cyano group, thiol group, silicone group, siloxane group, or a combination thereof.
2. The golf ball of claim 1 , wherein the polyolefin resin comprises high density polyethylene, low density polyethylene, linear low density polyethylene, ethylene-propylene copolymers, metallocene polyethylene, polypropylene, or mixtures thereof.
3. The golf ball of claim 1 , wherein the compatibilizer further comprises an intercalated clay.
4. The golf ball of claim 1 , wherein the intercalated clay is organically modified.
5. The golf ball of claim 1 , wherein the intercalated clay comprises a long chain organic modifier comprising greater than 7 carbon atoms.
6. The golf ball of claim 1 , wherein the at least one resin is selected from the group consisting of an ethylene-vinyl alcohol copolymer, a polyamide, an ionomer, a polyvinyl alcohol, and combinations thereof.
7. The golf ball of claim 1 , wherein the at least one resin comprises between about 5 and 25 percent acid moieties by weight of the resin, and wherein greater than about 70 percent of the acid moieties are neutralized.
8. The golf ball of claim 1 , wherein the composition comprises between about 0.5 to 60 parts by weight of the nanocomposite, about 40 to 96 parts by weight polyolefin resin, and about 1 to 30 parts by weight of a compatibilizer by weight of the composition.
9. A golf ball comprising a core and a cover, wherein the cover is formed from a composition comprising:
a nanocomposite comprising an organically modified intercalated clay and at least one polymer; and
a polyolefin resin; and
a compatibilizer comprising a compatibilizing agent and an intercalated clay, wherein the compatibilizing agent is selected from the group consisting of a maleic anhydride grafted ethylene propylene rubber, a maleic anhydride grafted ethylene propylene diene rubber, and combinations thereof.
10. The golf ball of claim 9 , wherein the at least one polymer is selected from the group consisting of an ethylene-vinyl alcohol copolymer, a polyamide, an ionomer, a polyvinyl alcohol, and combinations thereof.
11. The golf ball of claim 9 , wherein the organically modified intercalated clay has been organically modified through a reaction with at least one quaternary ammonium surfactant with multiple alkyl tails on the ammonium ion.
12. The golf ball of claim 9 , wherein the compatibilizing agent is a maleic anhydride grafted ethylene propylene rubber.
13. The golf ball of claim 9 , wherein the compatibilizing agent is a maleic anhydride grafted ethylene propylene diene rubber.
14. The golf ball of claim 9 , wherein the composition comprises about 2 to about 50 parts by weight of the nanocomposite, about 50 to 80 parts by weight of the polyolefin resin, and about 2 to about 25 parts by weight of the compatibilizer based on the total weight of the composition.
15. The golf ball of claim 9 , wherein the cover comprises an inner cover disposed about the core and an outer cover disposed about the inner cover, and wherein at least one of the inner cover or the outer cover comprises the composition.
16. A golf ball comprising:
a core; and
a cover, wherein at least one layer of the cover comprises a composition comprising:
about 40 to 96 parts by weight polyolefin resin;
about 4 to 40 parts by weight of a nanocomposite, wherein the nanocomposite comprises a polymer and an organically modified intercalated clay; and
about 2 to 25 parts by weight of a compatibilizer, wherein the compatibilizer comprises a compatibilizing agent and an intercalated clay, wherein the compatibilizing agent comprises a polymer functionalized with at least one amine group, hydroxy group, cyano group, thiol group, silicone group, siloxane group, or a combination thereof.
17. The golf ball of claim 16 , wherein the polymer is selected from the group consisting of an ethylene-vinyl alcohol copolymer, a polyamide, an ionomer, a polyvinyl alcohol, and mixtures thereof.
18. The golf ball of claim 17 , wherein the polyolefin resin is selected from the group consisting of high density polyethylene, low density polyethylene, linear low density polyethylene, ethylene-propylene copolymers, metallocene polyethylene, polypropylene, and mixtures thereof.
19. The golf ball of claim 18 , wherein the organically modified intercalated clay comprises at least two long chain alkyl tails comprising greater than 7 carbon atoms.
20. The golf ball of claim 16 , wherein the cover comprises an inner cover and an outer cover disposed on the inner cover, and wherein the inner cover comprises the composition.