Radiopaque alloy and medical device made of this alloy
View Patent ↗A radiopaque alloy based on titanium nickelide and having shape memory and superelastic properties includes, according to one embodiment, at least one radiopaque alloying element selected from among gold, platinum, and palladium at a concentration of from about 10 at. % to about 20 at. %, and at least one additional alloying element selected from among aluminum, chromium, cobalt, iron, and zirconium, where the additional alloying element has a concentration of from about 0.5 at. % to about 4 at. %. The alloy includes titanium at a concentration of from about 48 at. % to about 52 at. %, and the balance of the alloy is nickel. The radiopaque alloy preferably exhibits superelastic behavior suitable for medical device applications in the human body.
1. A radiopaque alloy having shape memory and superelastic properties, consisting of:
titanium at a concentration of from about 48 to about 52 atomic percent;
at a concentration of from about 10 to about 35 atomic percent;
at least one additional alloying element selected from the group consisting of iron and cobalt at a concentration of from about 0.5 to about 8 atomic percent;
at least one further alloying element selected from the group consisting of aluminum, chromium, and zirconium at a concentration of from about 0.5 to about 4 atomic percent; and
nickel and inevitable impurities as a balance.
2. The alloy of claim 1 , wherein the nickel has a concentration of from about 29 at. % to about 52 at. %.
3. The alloy of claim 1 , wherein the alloy comprises:
gold at a concentration of about 20 at. %;
iron at a concentration of about 0.5 at. %; and
zirconium at a concentration of about 1 at. %.
4. The alloy of claim 1 , wherein the alloy comprises:
gold at a concentration of about 10 at. %;
iron at a concentration of about 1.2 at. %; and
zirconium at a concentration of about 1 at. %.
5. The alloy of claim 1 , wherein the alloy comprises:
gold at a concentration of about 15 at. %; and
aluminum at a concentration of about 1.2 at. %.
6. The alloy of claim 1 , wherein the alloy comprises:
gold at a concentration of about 15 at. %; and
chromium at a concentration of about 1 at. %.
7. The alloy of claim 1 , wherein the recoverable strain is at least about 5%.
8. The alloy of claim 1 , wherein the alloy is superelastic and has an austenite finish temperature at or below 37° C.
9. A medical device comprising at least one component comprising the radiopaque alloy of claim 1 .
10. The medical device of claim 9 , wherein the component comprises at least one of a wire and a cannula made of the radiopaque alloy.