Process for removing ruthenium-containing catalyst residues from optionally hydrogenated nitrile rubber
View Patent ↗Novel optionally hydrogenated nitrile rubbers distinguised by a very low ruthenium content are provided as well as a process for the removal of ruthenium-containing catalyst residues from a solution of optionally hydrogenated nitrile rubber by using specific functionalized ion-exchange resins.
1. A process for the removal of ruthenium-containing catalyst residues from optionally hydrogenated nitrile rubber comprising the treatment of a solution of an optionally hydrogenated nitrile rubber containing ruthenium-containing catalyst residues with a functionalized ion exchange resin, characterized in that such functionalized ion exchange resin is (i) macroreticular, (ii) modified with at least one type of functional group which is selected from a primary amine, secondary amine, thiol, carbodithioate, thiourea and a dithiocarbamate group and (iii) has an average particle diameter in the range of from 0.2 to 2.5 mm dry basis and wherein the resin comprises styrene-divinylbenzene copolymers.
2. The process according to claim 1 , wherein the solution of the optionally hydrogenated nitrile rubber to be contacted with the functionalized ion exchange resin comprises from 5 to 1000 ppm of ruthenium, based on the optionally hydrogenated nitrile rubber.
3. The process according to claim 1 wherein the solution of the optionally hydrogenated nitrile rubber to be contacted with the functionalized ion exchange resin comprises from 5 to 500 ppm of ruthenium, based on the optionally hydrogenated nitrile rubber.
4. The process according to claim 1 or 2 , wherein the solution of the optionally hydrogenated nitrile rubber to be contacted with the functionalized ion exchange resin comprises from 0.5 to 30% by weight of the optionally hydrogenated nitrile rubber.
5. The process according to claim 1 or 2 , wherein the solution of the optionally hydrogenated nitrile rubber to be contacted with the functionalized ion exchange resin comprises from 2 to 20% by weight of the optionally hydrogenated nitrile rubber.
6. The process according to claim 1 or 2 , wherein the solution of the optionally hydrogenated nitrile rubber to be contacted with the functionalized ion exchange resin comprises from 3 to 12% by weight of the optionally hydrogenated nitrile rubber.
7. A process according to claim 1 or 2 , wherein a solution of the optionally hydrogenated nitrile rubber in dichloromethane, benzene, monochlorobenzene, toluene, methyl ethyl ketone, acetone, tetrahydrofuran, tetrahydropyran, dioxane or cyclohexane is used.
8. The process according to claim 1 or 2 , wherein the solution of the optionally hydrogenated nitrile rubber containing ruthenium-containing catalyst residues is obtained (i) by metathesis of a nitrile rubber in the presence of a ruthenium based catalyst and optionally (ii) a subsequent hydrogenation of the carbon-carbon double bonds present in the nitrile rubber.
9. The process according to claim 1 or 2 , wherein the solution of a hydrogenated nitrile rubber containing ruthenium-containing catalyst residues is obtained by a hydrogenation of the carbon-carbon double bonds present in the nitrile rubber in the presence of a ruthenium-containing catalyst.
10. The process according to claim 1 or 2 , wherein a solution of an optionally hydrogenated nitrile rubber is used which represents an optionally hydrogenated copolymer comprising repeating units of at least one conjugated diene and at least one a,β-unsaturated nitrile.
11. The process according to claim 1 or 2 , wherein a solution of an optionally hydrogenated nitrile rubber is used which represents an optionally hydrogenated copolymer comprising repeating units of at least one conjugated diene, at least one α,β-unsaturated nitrile and, optionally one or more further copolymerizable monomers.
12. The process according to claim 1 or 2 , wherein a hydrogenated nitrile rubber is used in which at least 50 mole% of the original carbon-carbon double bonds present in the nitrile rubber have been hydrogenated.
13. The process according to claim 1 or 2 , wherein a hydrogenated nitrile rubber is used in which at least 80 mole% of the original carbon-carbon double bonds present in the nitrile rubber have been hydrogenated.
14. The process according to claim 1 or 2 , wherein the functionalized ion-exchange resins are characterized by a concentration of functional groups in the range of from 0.2 to 7.0 mol/L.
15. The process according to claim 1 or 2 , wherein the functionalized ion-exchange resins are characterized by a concentration of functional groups in the range of from 0.5 to 5.0 mol/L.
16. The process according to claim 1 or 2 , wherein the functionalized ion-exchange resins are characterized by an average particles diameter in the range of from 0.5 and 0.8 mm dry basis.
17. The process according to claim 1 or 2 , wherein it is performed batch-wise (discontinuously) or continuously.
18. The process according to claim 1 or 2 , wherein the operating temperature lies in the range from 60° C. to 150° C.
19. The process according to claim 1 or 2 , wherein the ion-exchange resin is packed into a column and the solution of the optionally-hydrogenated nitrile rubber comprising the ruthenium-containing catalyst residues is passed through the column in a continuous manner.
20. An optionally hydrogenated nitrile rubber comprising at maximum 20 ppm ruthenium based on the optionally hydrogenated nitrile rubber, wherein the optionally hydrogenated nitrile rubber is obtained (i) by metathesis of a nitrile rubber in the presence of a ruthenium based catalyst and optionally (ii) a subsequent hydrogenation of the carbon-carbon double bonds present in the nitrile rubber.
21. An optionally hydrogenated nitrile rubber comprising at maximum 10 ppm ruthenium based on the optionally hydrogenated nitrile rubber, wherein the optionally hydrogenated nitrile rubber is obtained (i) by metathesis of a nitrile rubber in the presence of a ruthenium based catalyst and optionally (ii) a subsequent hydrogenation of the carbon-carbon double bonds present in the nitrile rubber.
22. An optionally hydrogenated nitrile rubber comprising at maximum 5 ppm ruthenium based on the optionally hydrogenated nitrile rubber, wherein the optionally hydrogenated nitrile rubber is obtained (i) by metathesis of a nitrile rubber in the presence of a ruthenium based catalyst and optionally (ii) a subsequent hydrogenation of the carbon-carbon double bonds present in the nitrile rubber.
23. An optionally hydrogenated nitrile rubber comprising at maximum 3 ppm ruthenium based on the optionally hydrogenated nitrile rubber, wherein the optionally hydrogenated nitrile rubber is obtained (i) by metathesis of a nitrile rubber in the presence of a ruthenium based catalyst and optionally (ii) a subsequent hydrogenation of the carbon-carbon double bonds present in the nitrile rubber.