Method for manufacturing a semiconductor device

1. A method for manufacturing a semiconductor device, comprising the steps of:

(a) forming a low dielectric constant film over a substrate, said low dielectric constant film having a pore;

(b) forming a recess in the low dielectric constant film;

(c) after the step (b), sequentially performing the steps of (c1) applying an organic solution to the low dielectric constant film and (c2) silylating the low dielectric constant film with a silylating solution such that the silylating solution reaches the pore; and

(d) after the step (c), embedding a metal in the recess to form at least one of a via plug and a metal wiring in the low dielectric constant film.

2. The method according to claim 1 , wherein the step (c2) further includes the step of heating the substrate after applying the silylating solution to the low dielectric constant film.

3. The method according to claim 1 , wherein the step (c1) further includes the step of heating the substrate after applying the organic solution to the low dielectric constant film.

4. The method according to claim 1 , wherein, in the step (c), the step (c2) is performed before the organic solution applied in the step (c1) dries.

5. The method according to claim 1 , wherein the step (b) is any one of etching, aching, and cleaning.

6. The method according to claim 1 , wherein the organic solution is a solvent contained in the silylating solution or a solution which is soluble in the solvent contained in the silylating solution and which is chemically stable with a silylating agent.

7. The method according to claim 1 , wherein the organic solution contains at least one alcohol.

8. The method according to claim 1 , wherein the organic solution is isopropyl alcohol or a solution containing at least isopropyl alcohol.

9. The method according to claim 1 , wherein the organic solution is made by using at least one of ketones, ethers, esters, and hydrocarbons.

10. The method according to claim 1 , wherein

the step (a) includes the steps of (a1) forming a first low dielectric constant film over the substrate and (a2) forming a second low dielectric constant film over the first low dielectric constant film,

the step (b) includes the steps of (b1) forming a part of the recess in the first low dielectric constant film and (b2) forming another part of the recess in the second low dielectric constant film,

the step (d) includes the steps of (d1), before the step (a2), embedding a metal in the part of the recess formed in the step (b1) to form the via plug in the first low dielectric constant film and (d2) embedding a metal in the part of the recess formed in the step (b2) to form the metal wiring in the second low dielectric constant film, thereby forming a wiring of a layer, and

the step (c) is performed after at least one of the steps (b1) and (b2).

11. The method according to claim 1 , wherein the recess formed in the low dielectric constant film is formed by a via hole and a wiring groove connecting to the via hole, the via plug and the metal wiring are simultaneously formed by embedding a metal in the recess, and the step (c) is performed after at least one of etching, ashing, and cleaning performed to form the recess.

12. The method according to claim 1 , further comprising steps of:

(e) applying light or electron beams to the low dielectric constant film after the step (a) and before the step (b); and

(f) after the step (e) and before the step (b), sequentially performing the steps of (f1) applying an organic solution to the low dielectric constant film and (f2) silylating the low dielectric constant film with a silylating solution.

13. The method according to claim 1 , wherein said pore has a diameter of about 2 nm or more to 3 nm or less.