INKJET-IMAGEABLE LITHOGRAPHIC PRINTING MEMBERS AND METHODS OF PREPARING AND IMAGING THEM
Lithographic printing plates are imaged using an inkjet printer to imagewise apply a chemical or masking agent onto the plate surface. In some embodiments, the chemical causes an affinity change, thereby facilitating lithographic printing.
1 - 15 . (canceled)
16 . A method of imaging a lithographic printing member, the method comprising the steps of:
(a) providing a printing member comprising a photosensitive top layer having a first lithographic affinity and a layer thereunder having a second lithographic affinity opposite to the first lithographic affinity, the top layer comprising a material which, upon subjection to an imaging fluid, becomes crosslinkable by exposure to actinic radiation;
(b) dispensing the imaging fluid in an imagewise pattern;
(c) exposing the printing member to actinic radiation, thereby crosslinking portions of the top layer that have received imaging fluid;
(d) subjecting the printing member to a solvent, the solvent disrupting non-image, uncrosslinked portions of the top layer; and
(e) removing the non-image portions of the top layer, thereby creating an imagewise lithographic pattern on the printing member.
17 . The method of claim 16 wherein the solvent comprises an aqueous fluid.
18 . The method of claim 16 , wherein the first lithographic affinity is hydrophilicity and the second lithographic affinity is oleophilicity.
19 . The method of claim 16 , wherein the first lithographic affinity is oleophilicity and the second lithographic affinity is hydrophilicity.
20 . The method of claim 16 , wherein the top layer comprises at least one crosslinkable moiety.
21 . The method of claim 20 , wherein the crosslinkable moiety is selected from the group consisting of multifunctional acrylic monomer, multifunctional acrylic oligomer, multifunctional acrylic macromer, and combinations thereof.
22 . The method of claim 16 , wherein the imaging fluid comprises a multifunctional amine.
23 . The method of claim 16 , wherein the top layer comprises at least one photo-polymerizable moiety and a first component of a two-component photo-polymerization initiating system.
24 . The method of claim 23 , wherein the imaging fluid comprises a second component of a two-component photo-polymerization initiating system.
25 - 95 . (canceled)