IP Library Granted Patent US 8,110,632
Granted Patent B2
US 8,110,632 · App. 12/353,995 · Granted Feb 7, 2012

Poly(arylene ether) articles and compositions

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Quick Facts
Patent No.
US 8,110,632
App. No.
12/353,995
Granted
Feb 7, 2012
Kind
B2
Abstract

A profile extruded article includes a composition that is formed by melt-kneading particular amounts of a poly(arylene ether), a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer, a homopolystyrene, and a polysalicylate. The article is particularly useful in the fabrication of solar collectors for low cost solar energy systems.

Claims (26)

1. A profile extruded article comprising a composition comprising the product of melt-kneading:

45 to 70 weight percent of a poly(arylene ether) having a post-compounding weight average molecular weight of 50,000 to 60,000 atomic mass units;

9 to 20 weight percent of a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a polystyrene content of 20 to 50 percent and a weight average molecular weight of at least 250,000 atomic mass units;

5 to 45 weight percent of homopolystyrene; and

1 to 9 weight percent of polysalicylate;

wherein all weight percents are based on the total weight of the composition;

wherein the weight ratio of poly(arylene ether) to polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer is less than or equal to 6.5;

wherein the profile extruded article is a multiwall article; and

wherein the profile extruded article is a solar collector.

2. The profile extruded article of claim 1 , wherein the poly(arylene ether) has a pre-compounding weight average molecular weight of 40,000 to 50,000 atomic mass units.

3. The profile extruded article of claim 1 , wherein the composition exhibits

a tensile stress at yield of at least 60 megapascals, measured at 23° C. according to ISO 527,

a tensile modulus of at least 2200 megapascals, measured at 23° C. according to ISO 527,

a flexural strength of at least 80 megapascals, measured at 23° C. according to ISO 178,

a melt volume-flow rate of at least 20 cubic centimeters per minute, measured at 300° C. and 10 kilogram load according to ISO 1133,

a heat deflection temperature of at least 140° C., measured at 0.45 megapascals according to ISO 75/Bf,

an Izod notched impact strength of at least 18 kilojoules/meter 2 , measured at 23° C. according to ISO 180/1A, and

an Izod notched impact strength of at least 7 kilojoules/meter 2 , measured at 23° C. according to ISO 180/1A after aging for 2000 hours in air at 140° C.

4. The profile extruded article of claim 1 , wherein the composition comprises less than 2 weight percent any polymer other than the poly(arylene ether), the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer, the homopolystyrene, and the polysalicylate.

5. The profile extruded article of claim 1 , wherein the composition excludes fillers.

6. The profile extruded article of claim 1 , wherein the composition comprises the product of melt-kneading:

55 to 65 weight percent of a poly(arylene ether) having a post-compounding weight average molecular weight of 53,000 to 57,000 atomic mass units;

11 to 16 weight percent of a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer having a polystyrene content of 25 to 40 percent and a weight average molecular weight of 250,000 to 450,000 atomic mass units;

15 to 25 weight percent of homopolystyrene; and

3 to 6 weight percent of polysalicylate;

wherein the weight ratio of poly(arylene ether) to polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer is 3 to 5.

Assignments (7)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE THE APPLICATION NUMBER 15039474 PREVIOUSLY RECORDED AT REEL: 054528 FRAME: 0467. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 23, 2021
From: SABIC GLOBAL TECHNOLOGIES B.V.
To: SHPP GLOBAL TECHNOLOGIES B.V.
Reel/Frame 057453/0680 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 26, 2020
From: SABIC GLOBAL TECHNOLOGIES B.V.
To: SHPP GLOBAL TECHNOLOGIES B.V.
Reel/Frame 054528/0467 →
CHANGE OF NAME Recorded Jun 6, 2016
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 038883/0816 →
RELEASE OF SECURITY INTEREST Recorded Mar 17, 2014
From: CITIBANK, N.A.
To: SABIC INNOVATIVE PLASTICS IP B.V.
Reel/Frame 032459/0798 →
SECURITY AGREEMENT Recorded Mar 1, 2010
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024005/0462 →
SECURITY AGREEMENT Recorded Jun 18, 2009
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 022843/0918 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 15, 2009
From: LIETZAU, CHRISTIAN; MHETAR, VIJAY R.; NAMJOSHI, ABHIJIT; ZIJLMA, GEUCH
To: SABIC INNOVATIVE PLASTICS IP B.V.
Reel/Frame 022110/0431 →