IP Library Granted Patent US 8,119,735
Granted Patent B2
US 8,119,735 · App. 12/359,688 · Granted Feb 21, 2012

Golf ball with cover having a pearlescent effect

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Quick Facts
Patent No.
US 8,119,735
App. No.
12/359,688
Granted
Feb 21, 2012
Kind
B2
Abstract

A golf ball having a cover having a pearlescent effect is disclosed. The cover comprises a first thermoplastic and a second thermoplastic having an index of refraction that differs from an index of refraction of the first thermoplastic by at least about 0.5 percent. The cover further comprises a compatibilizer.

Claims (34)

1. A golf ball comprising:

at least a core and a cover, wherein the cover comprises a first thermoplastic, a second thermoplastic, and a compatibilizer comprising reactive functional moieties chosen from the group consisting of hydroxyl, cyano, anhydride, epoxy, acid, and amine, wherein the first thermoplastic has an index of refraction that differs from an index of refraction of the second thermoplastic by at least about 0.5 percent, and wherein the cover has a pearlescent appearance, and wherein the second thermoplastic comprises a copolymer consisting of styrene and butadiene.

2. The golf ball of claim 1 , wherein the index of refraction of the first thermoplastic differs from the index of refraction of the second thermoplastic by not more than about 6 percent.

3. The golf ball of claim 2 , wherein the index of refraction of the first thermoplastic differs from the index of refraction of the second thermoplastic by at least about 2 percent and not more than about 4 percent.

4. The golf ball of claim 1 , wherein the index of refraction of the first thermoplastic is between about 1.45 and about 1.55.

5. The golf ball of claim 1 , wherein the first thermoplastic comprises an ionomer.

6. The golf ball of claim 5 , wherein the first thermoplastic comprises a copolymer of ethylene and either acrylic or methacrylic acid.

7. The golf ball of claim 6 wherein the acrylic or methacrylic acid is at least partially neutralized.

8. The golf ball of claim 6 wherein the acrylic or methacrylic acid is highly neutralized.

9. The golf ball of claim 1 , wherein the copolymer of styrene and butadiene comprises between about 10 percent and about 20 percent of the second thermoplastic.

10. The golf ball of claim 1 , wherein the cover comprises between about 50 percent and about 85 percent of the first thermoplastic.

11. The golf ball of claim 10 , wherein the cover comprises between about 60 percent and about 80 percent of the first thermoplastic.

12. The golf ball of claim 10 , wherein the cover comprises about 70 percent of the first thermoplastic.

13. The golf ball of claim 1 , wherein the cover comprises between about 10 percent and about 45 percent of the second thermoplastic.

14. The golf ball of claim 13 , wherein the cover comprises between about 15 percent and about 35 percent of the second thermoplastic.

15. The golf ball of claim 1 , wherein the cover comprises between about 1 percent and about 10 percent of the compatibilizer.

16. The golf ball of claim 15 , wherein the cover comprises between about 3 percent and about 7 percent of the compatibilizer.

17. The golf ball of claim 1 , wherein the cover has a material hardness from about 45 to about 70 Shore D.

18. The golf ball of claim 1 , wherein the cover has a material hardness from about 55 to about 65 Shore D.

19. The golf ball of claim 1 , wherein the cover has a flexural modulus from about 30 to about 75 kpsi.

20. The golf ball of claim 1 , wherein the cover has a flexural modulus from about 45 to about 70 kpsi.

21. The golf ball of claim 1 , wherein the cover has a flexural modulus from about 50 to about 65 kpsi.

22. The golf ball of claim 1 , wherein the golf ball has an Atti compression of less than about 120.

23. The golf ball of claim 1 , wherein the golf balls has an Atti compression from about 90 to about 105.

24. The golf ball of claim 1 , wherein the golf ball has a coefficient of restitution of at least 0.700.

25. The golf ball of claim 1 further comprising an intermediate layer disposed between the core and the cover.

26. The golf ball of claim 25 , wherein the core has an outer diameter between about 0.5 and about 1.62 inches and the core comprises a center having an outer diameter from about 0.5 inches to about 1.3 inches, wherein the intermediate layer has a thickness from about 0.015 to about 0.06 inches, and wherein the outer cover layer has a thickness from about 0.025 inches to about 0.05 inches.

27. A golf ball comprising:

at least a core and a cover, wherein the cover comprises a first thermoplastic a second thermoplastic, and a compatibilizer comprising reactive functional moieties chosen from the group consisting of hydroxyl, cyano, anhydride, epoxy, acid, and amine, wherein the first thermoplastic has an index of refraction that differs from an index of refraction of the second thermoplastic by at least about 0.5 percent, and wherein the cover has a pearlescent appearance, wherein the second thermoplastic comprises a blend of polycarbonate and a terpolymer of acrylonitrile, butadiene, and styrene.

28. A method of obscuring the parting line of a golf ball comprising the steps of:

(a) providing a first thermoplastic, a second thermoplastic having an index of refraction that differs from an index of refraction of the first thermoplastic by at least 0.5 percent, and a compatibilizer comprising reactive functional moieties chosen from the group consisting of hydroxyl, cyano, anhydride, epoxy, acid, and amine, wherein the second thermoplastic comprises a copolymer consisting of styrene and butadiene;

(b) mixing the first thermoplastic, the second thermoplastic, and the compatibilizer to form a cover material; and

(c) forming a golf ball cover out of the cover material.

29. The method of claim 28 , wherein the index of refraction of the second thermoplastic is different from the index of refraction of the first thermoplastic by not more than 6 percent.

Assignments (6)
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (027346/0222) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0181 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Dec 8, 2011
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 027346/0222 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2009
From: HEBERT, EDMUND A.; RAJAGOPALAN, MURALI
To: ACUSHNET COMPANY
Reel/Frame 022155/0623 →