Conductive polymer and solid electrolytic capacitor using the same

1. A conductive polymer represented by general formula (3) obtained by polymerizing as a monomer a compound represented by general formula (2), which has a basic skeleton from a 3-alkyl five-membered heterocyclic ring compound represented by general formula (1), in which two to ten molecules of the compounds represented by general formula (1) are bonded at positions 2 and 5 of five-membered heterocyclic rings with head-to-tail regulation of the alkyl groups;

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, and n represents an integer of 0 to 9;

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, n represents an integer of 0 to 9, and m represents an integer of 0 to 8,

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, n represents an integer of 0 to 9, m represents an integer of 0 to 8, and k represents a natural number.

2. The conductive polymer according to claim 1 , wherein the conductive polymer represented by general formula (3) is obtained by a polymerization in a solution containing a dopant by chemical oxidative polymerization.

3. The conductive polymer according to claim 2 , wherein the dopant is at least one selected from the group consisting of compounds represented by general formulae (4) to (8):

ROSO 3 H  (4)

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms.

4. The conductive polymer according to claim 1 , wherein the conductive polymer represented by general formula (3) is obtained by a polymerization in a supporting electrolyte containing a dopant by electrolytic polymerization.

5. The conductive polymer according to claim 4 , wherein the dopant is at least one selected from the group consisting of compounds represented by general formulae (4) to (8):

ROSO 3 H  (4)

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms.

6. A solid electrolytic capacitor comprising: an anode body having an enlarged surface and including a valve action metal, a dielectric layer obtained by forming an oxide film on a surface of the anode body, a solid electrolyte layer, and a cathode layer; the solid electrolyte layer and the cathode layer being formed after the formation of the dielectric layer to provide a cathode; wherein the solid electrolyte comprises a conductive polymer represented by general formula (3) obtained by polymerizing as a monomer a compound represented by general formula (2), which has a basic skeleton from a 3-alkyl five-membered heterocyclic ring compound represented by general formula (1), in which two to ten molecules of the compounds represented by general formula (1) are bonded at positions 2 and 5 of five-membered heterocyclic rings with head-to-tail regulation of the alkyl groups;

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, and n represents an integer of 0 to 9;

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, n represents an integer of 0 to 9, and m represents an integer of 0 to 8,

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, n represents an integer of 0 to 9, m represents an integer of 0 to 8, and k represents a natural number.

7. The solid electrolytic capacitor according to claim 6 , wherein the conductive polymer represented by general formula (3) is obtained on a surface of the dielectric layer by a polymerization in a solution containing a dopant by chemical oxidative polymerization.

8. The solid electrolytic capacitor according to claim 7 , wherein the dopant is at least one selected from the group consisting of compounds represented by general formulae (4) to (8):

ROSO 3 H  (4)

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms.

9. The solid electrolytic capacitor according to claim 6 , wherein the valve action metal is at least one selected from the group consisting of tantalum, aluminum, and niobium.

10. A solid electrolytic capacitor comprising: an anode body having an enlarged surface and including a valve action metal, a dielectric layer obtained by forming an oxide film on a surface of the anode body, a first solid electrolyte layer, a second solid electrolyte layer, and a cathode layer; the first solid electrolyte layer, the second solid electrolyte layer, and the cathode layer being formed after the formation of the dielectric layer; wherein one of the first solid electrolyte layer and the second solid electrolyte layer comprises manganese dioxide or a conductive polymer such as polypyrrole, polythiophene, and polyphenylenevinylene and derivatives thereof; and wherein the other comprises a conductive polymer represented by general formula (3) obtained by polymerizing as a monomer a compound represented by general formula (2), which has a basic skeleton from a 3-alkyl five-membered heterocyclic ring compound represented by general formula (1), in which two to ten molecules of the compounds represented by general formula (1) are bonded at positions 2 and 5 of five-membered heterocyclic rings with head-to-tail regulation of the alkyl groups;

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, and n represents an integer of 0 to 9;

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, n represents an integer of 0 to 9, and m represents an integer of 0 to 8,

wherein X represents an atomic group of —NH— or an atom of S, O, or Se, n represents an integer of 0 to 9, m represents an integer of 6 to 8, and k represents a natural number.

11. The solid electrolytic capacitor according to claim 10 , wherein the second solid electrolyte layer, in which the conductive polymer represented by general formula (3) is obtained by a polymerization in a solution containing a dopant by chemical oxidative polymerization, is formed on the first solid electrolyte layer.

12. The solid electrolytic capacitor according to claim 11 , wherein the dopant is at least one selected from the group consisting of compounds represented by general formulae (4) to (8):

ROSO 3 H  (4)

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms.

13. The solid electrolytic capacitor according to claim 10 , wherein the second solid electrolyte layer, in which the conductive polymer represented by general formula (3) is obtained by a polymerization in a supporting electrolyte containing a dopant by electrolytic polymerization, is formed on the first solid electrolyte layer.

14. The solid electrolytic capacitor according to claim 13 , wherein the dopant is at least one selected from the group consisting of compounds represented by general formulae (4) to (8):

ROSO 3 H  (4)

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms,

wherein R represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms.

15. The solid electrolytic capacitor according to claim 10 , wherein the second solid electrolyte layer is formed by applying a solution or dispersion of the conductive polymer represented by general formula (3).

16. The solid electrolytic capacitor according to claim 10 , wherein the valve action metal is at least one selected from the group consisting of tantalum, aluminum, and niobium.