Method for manufacturing lithium ion secondary battery
A method for manufacturing a lithium ion secondary battery comprises the step of sintering a laminate sandwiched by setters disposed on both sides of the laminate having only interfaces between an electrolyte green sheet and a positive electrode green sheet and/or a negative electrode green sheet. A lithium ion secondary battery manufactured by the method described above is also provided.
1. A method for manufacturing a lithium ion secondary battery comprising the step of:
sintering a laminate sandwiched by a first setter disposed on a positive electrode side, hereinafter referred to as a positive electrode setter, and a second setter disposed on a negative electrode side, hereinafter referred to as a negative electrode setter, of the laminate having only an interface between an electrolyte green sheet and a positive electrode green sheet and an interface between the electrolyte green sheet and a negative electrode green sheet
wherein the positive electrode setter and the negative electrode setter have different porosities such that the positive electrode setter has a porosity of at least 20%, and the negative electrode setter has a porosity of not exceeding 5%.
2. The method according to claim 1 wherein at least one of the positive electrode setter and the negative electrode setter has an average pore diameter of 0 to 100 μm.
3. The method according to claim 1 wherein at least one of the positive electrode setter and the negative electrode setter has a maximum pore diameter of 0 to 200 μm.
4. The method according to claim 1 wherein the positive electrode setter has a porosity of 20 to 75%.
5. The method according to claim 1 wherein the positive electrode setter and the negative electrode setter have different average pore diameters.
6. The method according to claim 5 wherein the positive electrode setter has an average pore diameter of at least 0.5 μm.
7. The method according to claim 6 wherein the negative electrode setter has a maximum pore diameter of not exceeding 0.5 μm.
8. The method according to claim 5 wherein and the negative electrode setter has an average pore diameter of at least 0.5 μm.
9. The method according to claim 8 wherein the positive electrode setter has a maximum pore diameter of not exceeding 0.5 μm.
10. The method according to claim 1 wherein each of the positive electrode setter and the negative electrode setter comprises ceramic, glass, crystallized glass, metal, or a composite material thereof.
11. A method for manufacturing a lithium ion secondary battery comprising the step of:
sintering a laminate sandwiched by a setter disposed on a positive electrode side, hereinafter referred to as a positive electrode setter, and a setter disposed on a negative electrode side, hereinafter referred to as a negative electrode setter, of the laminate, which comprises a positive electrode green sheet and a negative electrode green sheet and has only an interface between an electrolyte green sheet and the positive electrode green sheet and an interface between the electrolyte green sheet and the negative electrode green sheet,
wherein the porosity of the positive electrode setter is greater than that of the negative electrode setter, and a sintering atmosphere has an oxygen concentration of not exceeding 10% in the sintering process.
12. A method for manufacturing a lithium ion secondary battery comprising the step of:
sintering a laminate sandwiched by a setter disposed on a positive electrode side, hereinafter referred to as a positive electrode setter, and a setter disposed on a negative electrode side, hereinafter referred to as a negative electrode setter, of the laminate, which comprises:
a positive electrode green sheet and a negative electrode green sheet and has only an interface between an electrolyte green sheet and the positive electrode green sheet and an interface between the electrolyte green sheet and the negative electrode green sheet,
wherein the porosity of the negative electrode setter is greater than that of the positive electrode setter, and a sintering atmosphere has an oxygen concentration of not exceeding 20% in the sintering process.