Distillate-to-gasoline catalyst system and process therefor
View Patent ↗A process is disclosed for converting distillate to gasoline-range hydrocarbons using a two-stage catalyst system including a first catalyst containing platinum, palladium, or platinum and palladium, and an acidic support, and a second catalyst containing iridium and an inorganic oxide support, and optionally nickel.
1. A process for maximizing octane by converting a low octane distillate feedstream to a high octane gasoline-range hydrocarbons comprising:
a) contacting the low octane distillate feedstream, in a first reaction zone, with a first catalyst comprising a metal component selected from the group consisting of platinum, palladium, and combinations thereof, and an acidic support in the presence of hydrogen to produce an intermediate product; and
b) contacting said intermediate product, in a second reaction zone, with a second catalyst comprising iridium and an inorganic oxide support to produce a high octane gasoline-range product.
2. The process of claim 1 wherein said first reaction zone includes a temperature in the range of from about 200° C. to about 300° C., a pressure in the range of from about 100 psig to about 500 psig, and a WHSV for said low octane distillate feedstream of about 0.1 to about 100 hr. −1 .
3. The process of claim 1 wherein said first reaction zone includes a temperature in the range of from about 220° C. to about 260° C., a pressure in the range of from about 200 psig to about 300 psig, and a WHSV for said low octane distillate feedstream of about 0.1 to about 10 hr. −1 .
4. The process of claim 1 wherein said second reaction zone includes a temperature in the range of from about 260° C. to about 350° C., a pressure in the range of from about 100 psig to about 500 psig, and a WHSV of from about 0.1 to about 100 hr. −1 .
5. The process of claim 1 wherein said second reaction zone includes a temperature in the range of from about 280° C. to about 330° C., a pressure in the range of from about 200 psig to about 300 psig, and a WHSV of from about 0.1 to about 10 hr. −1 .
6. The process of claim 1 wherein said acidic support is a Y zeolite and wherein said second catalyst further comprises nickel.
7. The process of claim 6 wherein said Y zeolite is hydrogen exchanged.
8. The process of claim 1 wherein said first catalyst contains from about 0.5 to about 5 weight percent metal component.
9. The process of claim 1 wherein said second catalyst contains from about 0.5 to about 5 weight percent iridium.
10. The process of claim 1 wherein said first catalyst contains from about 0.5 to about 3 weight percent metal component.
11. The process of claim 6 wherein said second catalyst contains from about 0.5 to about 5 weight percent iridium and from about 0.5 to about 5 weight percent nickel.
12. The process of claim 1 wherein said second catalyst contains from about 0.5 to about 3 weight percent iridium.
13. The process of claim 1 wherein said inorganic oxide support is selected from the group consisting of silica, alumina and combinations thereof
14. The process of claim 1 wherein said inorganic oxide support is silica.
15. The process of claim 1 wherein said inorganic oxide support is alumina.
16. The process of claim 1 wherein said low octane distillate feedstream has an RON in the range of from about 25 to about 50, said low octane distillate feedstream comprises: 1) hydrocarbons having in the range of 8 to 24 carbon atoms per molecule, 2) at least about 20 wt. % 1-ring napthenes, 3) at least about 20 wt. % 2-ring napthenes, and 4) at least about 10 wt. % aromatics; and wherein at least about 25 wt. % of said low octane distillate feedstream boils at a temperature greater than or equal to about 221° C.
17. The process of claim 1 wherein said intermediate product comprises less than or equal to about 5 wt. % aromatics; less than or equal to about 15 wt. % 2-ring naphthenes; and wherein less than about 2 wt. % of said intermediate product boils at a temperature greater than or equal to about 221° C.
18. The process of claim 1 wherein said high octane gasoline-range product has an RON of at least about 65; comprises at least about 40 wt. % paraffins; comprises less than or equal to about 5 wt. % aromatics; and wherein less than about 2 wt. % of said high octane gasoline-range product boils at a temperature greater than or equal to about 221° C.
19. A process for maximizing octane by converting a low octane distillate feedstream to a high octane gasoline-range hydrocarbons comprising:
a) contacting the low octane distillate feedstream, in a first reaction zone, with a first catalyst comprising a metal component selected from the group consisting of platinum, palladium, and combinations thereof, and an acidic support in the presence of hydrogen to produce an intermediate product,
wherein said first reaction zone includes a temperature in the range of from about 220° C. to about 260° C., a pressure in the range of from about 200 psig to about 300 psig, and a WHSV for said low octane distillate feedstream of about 0.1 to about 10 hr. −1 ; and
b) contacting said intermediate product, in a second reaction zone, with a second catalyst comprising iridium and an inorganic oxide support to produce a high octane gasoline-range product, wherein said second reaction zone includes a temperature in the range of from about 280° C. to about 330° C., a pressure in the range of from about 200 psig to about 300 psig, and a WHSV of from about 0.1 to about 10 hr. −1 .