Energy ray-curable ink composition
View Patent ↗An object of the present invention is to provide an energy ray-curable ink composition which is excellent in curability and adhesion, and is also excellent in storage stability. The present invention relates to an energy ray-curable ink composition comprising a coloring material; a polyfunctional monomer having three or more ethylenical double bonds in one molecule as a polymerizable compound; an α-aminoalkylphenone-based compound and a thioxanthone-based compound as photopolymerization initiators; and a hindered amine-based compound having a 2,2,6,6-tetramethylpiperidinyl group as an antigelling agent.
1. An energy ray-curable ink composition comprising a coloring material; a polyfunctional monomer having three or more ethylenical double bonds in one molecule and a polymerizable monomer having one or two ethylenical double bonds in one molecule as polymerizable compounds, said polymerizable compounds consisting of (meth)acrylate monomers; an α-aminoalkylphenone-based compound and a thioxanthone-based compound as photopolymerization initiators; and a hindered amine-based compound having a 2,2,6,6-tetramethylpiperidinyl group as an antigelling agent, wherein said energy ray-curable ink composition contains the polyfunctional monomer in an amount of 10 to 65% by mass, the polymerizable monomer having one or two ethylenical double bonds in one molecule in an amount of 10 to 70% by mass, the α-aminoalkylphenone-based compound in an amount of 2 to 20% by mass, the thioxanthone-based compound in an amount of 0.1 to 10% by mass and the hindered amine-based compound in an amount of 0.01 to 2% by mass, based on the entire amount of the ink composition, and wherein said energy ray-curable ink composition contains the α-aminoalkylphenone-based compound in an amount of 40 to 99% by mass and the thioxanthone-based compound in an amount of 1 to 60% by mass, based on the entire amount of the photopolymerization initiator;
wherein the thioxanthone-based compound is selected from the group consisting of thioxanthone, 2-methylthioxanthone, 2-ethylthioxanthone, 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, and 1-chloro-4-propoxythioxanthone.
2. The energy ray-curable ink composition according to claim 1 , wherein the hindered amine-based compound has a 1-hydroxy-2,2,6,6-tetramethylpiperidinyl group.
3. The energy ray-curable ink composition according to claim 1 , which contains, as the hindered amine-based compound, bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate.
4. An energy ray-curable ink composition comprising a coloring material; at least one of a polyfunctional monomer selected from the group consisting of trimethylolpropane tri(meth)acrylate and pentaerythritol tri(meth)acrylate as a polymerizable compound; at least one of an α-aminoalkylphenone-based compound selected from the group consisting of 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one and 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butanone, and a thioxanthone-based compound as photopolymerization initiators; and bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate as an antigelling agent; wherein
the energy ray-curable ink composition contains the polyfunctional monomer in an amount of 10 to 65% by mass, the α-aminoalkylphenone-based compound in an amount of 2 to 20% by mass, the thioxanthone-based compound in an amount of 0.1 to 10% by mass and the bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate in an amount of 0.01 to 2% by mass, based on the entire amount of the ink composition; and
also contains the α-aminoalkylphenone-based compound in an amount of 40 to 99% by mass and the thioxanthone-based compound in an amount of 1 to 60% by mass, based on the entire amount of the photopolymerization initiator;
wherein the thioxanthone-based compound is selected from the group consisting of thioxanthone, 2-methylthioxanthone, 2-ethylthioxanthone, 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, and 1-chloro-4-propoxythioxanthone.